Rational strategies for proton-conductive metal–organic frameworks

DW Lim, H Kitagawa - Chemical Society Reviews, 2021 - pubs.rsc.org
Since the transition of energy platforms, proton-conducting materials have played a
significant role in broad applications for electrochemical devices. In particular, solid-state …

Material evolution with nanotechnology, nanoarchitectonics, and materials informatics: what will be the next paradigm shift in nanoporous materials?

W Chaikittisilp, Y Yamauchi, K Ariga - Advanced Materials, 2022 - Wiley Online Library
Materials science and chemistry have played a central and significant role in advancing
society. With the shift toward sustainable living, it is anticipated that the development of …

A stable quasi-solid electrolyte improves the safe operation of highly efficient lithium-metal pouch cells in harsh environments

Z Chang, H Yang, X Zhu, P He, H Zhou - Nature Communications, 2022 - nature.com
Nanoconfined/sub-nanoconfined solvent molecules tend to undergo dramatic changes in
their properties and behaviours. In this work, we find that unlike typical bulk liquid …

Short hydrogen-bond network confined on COF surfaces enables ultrahigh proton conductivity

B Shi, X Pang, S Li, H Wu, J Shen, X Wang… - Nature …, 2022 - nature.com
The idea of spatial confinement has gained widespread interest in myriad applications.
Especially, the confined short hydrogen-bond (SHB) network could afford an attractive …

Confining Water Nanotubes in a Cu10O13-Based Metal–Organic Framework for Propylene/Propane Separation with Record-High Selectivity

Q Dong, Y Huang, J Wan, Z Lu, Z Wang… - Journal of the …, 2023 - ACS Publications
Energy-efficient separation of propylene (C3H6)/propane (C3H8) is in high demand for the
chemical industry. However, this process is challenging due to the imperceptible difference …

Introducing Water‐Network‐Assisted Proton Transfer for Boosted Electrocatalytic Hydrogen Evolution with Cobalt Corrole

X Li, B Lv, XP Zhang, X Jin, K Guo… - Angewandte Chemie …, 2022 - Wiley Online Library
Proton transfer is vital for many biological and chemical reactions. Hydrogen‐bonded water‐
containing networks are often found in enzymes to assist proton transfer, but similar strategy …

Implanting Numerous Hydrogen‐Bonding Networks in a Cu‐Porphyrin‐Based Nanosheet to Boost CH4 Selectivity in Neutral‐Media CO2 Electroreduction

YR Wang, M Liu, GK Gao, YL Yang… - Angewandte …, 2021 - Wiley Online Library
The exploration of novel systems for the electrochemical CO2 reduction reaction (CO2RR)
for the production of hydrocarbons like CH4 remains a giant challenge. Well‐designed …

Ligand-directed conformational control over porphyrinic zirconium metal–organic frameworks for size-selective catalysis

L Yang, P Cai, L Zhang, X Xu… - Journal of the …, 2021 - ACS Publications
Zirconium-based metal–organic frameworks (Zr-MOFs) have aroused enormous interest
owing to their superior stability, flexible structures, and intriguing functions. Precise control …

Sulfonic and phosphonic porous solids as proton conductors

SS Liu, QQ Liu, SZ Huang, C Zhang, XY Dong… - Coordination Chemistry …, 2022 - Elsevier
Over the past decades, solid-state ordered porous materials (SSOPMs), including newly-
emerging metal-organic frameworks (MOFs), metal-organic polyhedra (MOPs), covalent …

Nanoarchitectonics for coordination asymmetry and related chemistry

K Ariga, M Shionoya - Bulletin of the Chemical Society of Japan, 2021 - academic.oup.com
Nanoarchitectonics is a concept envisioned to produce functional materials from nanoscale
units through fusion of nanotechnology with other scientific disciplines. For component …