Conspectus Catalytic atroposelective syntheses of axially chiral compounds have stimulated
extensive interest in multiple communities, such as synthetic chemistry, biochemistry, and …

Atropisomerism is a stereochemical behavior portrayed by three-dimensional molecules that
bear rotationally restricted σ bond. Akin to the well-represented point-chiral molecules …

Conspectus Indole-based chiral heterocycles constitute a class of important heterocyclic
compounds that are found in numerous pharmaceuticals, functional materials, and chiral …

The first highly atroposelective construction of N− N axially chiral indole scaffolds was
established via a new strategy of de novo ring formation. This strategy makes use of the …

Direct catalytic transformation of C–H bonds to new functionalities has provided a powerful
strategy to synthesize complex molecular scaffolds in a straightforward way. Unstinting …

Axially chiral biaryl motifs are widely present in natural products and pharmaceuticals.
Moreover, they have been broadly used as privileged ligands in asymmetric catalysis. Over …

Comprehensive Summary A new strategy for the enantioselective synthesis of axially chiral
3, 3'‐bisindoles was devised by the direct coupling of two indole rings. This strategy makes …

A highly enantio-and diastereoselective dynamic kinetic resolution (DKR) of
configurationally labile 3-aryl indole-2-carbaldehydes is described. The DKR proceeds via a …

Axially chiral indole‐based frameworks have been recognized as a class of important five‐
membered heterobiaryls and developing catalytic asymmetric approaches for constructing …

Atropoisomeric (hetero) biaryls are scaffolds with increasing importance in the
pharmaceutical and agrochemical industries. Although it is the most obvious disconnection …