[HTML][HTML] Copper-mediated living radical polymerization (atom transfer radical polymerization and copper (0) mediated polymerization): from fundamentals to …

C Boyer, NA Corrigan, K Jung, D Nguyen… - Chemical …, 2016 - ACS Publications
The discovery of the first “living” radical polymerization by Otsu and co-workers (1) in 1982
heralded the start of a very exciting time for polymer chemists. Since then, a plethora of living …

Controlled/living radical polymerization in dispersed systems: an update

PB Zetterlund, SC Thickett, S Perrier… - Chemical …, 2015 - ACS Publications
This review is an extensive update to the comprehensive review on controlled/living radical
polymerization (CLRP) in dispersed systems published in 2008. 1 A note on nomenclature …

Cu (0)-mediated living radical polymerization: a versatile tool for materials synthesis

A Anastasaki, V Nikolaou, G Nurumbetov… - Chemical …, 2016 - ACS Publications
During the past decade we have witnessed the rapid development and understanding of
living radical polymerization (LRP)(or reversible deactivation radical polymerizations …

Copper (II)/tertiary amine synergy in photoinduced living radical polymerization: Accelerated synthesis of ω-functional and α, ω-heterofunctional poly (acrylates)

A Anastasaki, V Nikolaou, Q Zhang… - Journal of the …, 2014 - ACS Publications
Photoinduced living radical polymerization of acrylates, in the absence of conventional
photoinitiators or dye sensitizers, has been realized in “daylight'” and is enhanced upon …

SARA ATRP or SET-lRP. end of controversy?

D Konkolewicz, Y Wang, P Krys, M Zhong, AA Isse… - Polymer …, 2014 - pubs.rsc.org
A debate has proceeded in the literature regarding the mechanism of reversible-deactivation
radical polymerization in the presence of Cu0. The two proposed models are supplemental …

Reversible-deactivation radical polymerization in the presence of metallic copper. A critical assessment of the SARA ATRP and SET-LRP mechanisms

D Konkolewicz, Y Wang, M Zhong, P Krys… - …, 2013 - ACS Publications
Reversible-deactivation radical polymerization (RDRP) in the presence of Cu0 is a versatile
technique that can be used to create well-controlled polymers with complex architectures …

The strength of multi-scale modeling to unveil the complexity of radical polymerization

DR D'hooge, PHM Van Steenberge… - Progress in Polymer …, 2016 - Elsevier
The strength of multi-scale modeling to support the fundamental understanding and design
of radical polymerization processes is illustrated, considering both controlled and free …

Single-electron transfer living radical polymerization platform to practice, develop, and invent

G Lligadas, S Grama, V Percec - Biomacromolecules, 2017 - ACS Publications
The most fundamental aspects of single-electron transfer (SET) principles are presented.
They are discussed according to different definitions used by expert practitioners and are …

Cu (0)-mediated living radical polymerization: recent highlights and applications; a perspective

A Anastasaki, V Nikolaou, DM Haddleton - Polymer Chemistry, 2016 - pubs.rsc.org
Cu (0)-mediated living radical polymerization or single electron transfer living radical
polymerization (Cu (0)-mediated LRP or SET-LRP) is a versatile polymerization technique …

Copper‐mediated polymerization without external deoxygenation or oxygen scavengers

E Liarou, R Whitfield, A Anastasaki… - Angewandte …, 2018 - Wiley Online Library
As a method for overcoming the challenge of rigorous deoxygenation in copper‐mediated
controlled radical polymerization processes [eg, atom‐transfer radical polymerization …