Cross-linked polymer membranes for energy-efficient gas separation: innovations and perspectives

M Liu, A Seeger, R Guo - Macromolecules, 2023 - ACS Publications
Polymeric membranes for gas separations have experienced rapid growth over the past few
decades, and extensive research has been performed to develop high-performance polymer …

The mechanism of light gas transport through configurational free volume in glassy polymers

WJ Box, Z Huang, R Guo, M Galizia - Journal of Membrane Science, 2022 - Elsevier
A possible mechanism of small molecule transport in glassy polymer membranes containing
configurational free volume (ie, triptycene moieties) is proposed. To this aim, a family of …

Inter-crosslinked spirocyclic mixed matrix membranes exhibiting enhanced gas permeability, selectivity, and plasticization resistance

LC Condes, AE Landry, MT Webb, WJ Box… - Journal of Membrane …, 2024 - Elsevier
Poor interfacial compatibility is the most common issue inhibiting performance enhancement
in mixed matrix membranes (MMM) for gas and liquid separations. To address this issue, we …

Effect of halogen substituents on polymer membrane hydrophobicity, swelling and transport mechanism: chlorine versus fluorine

J Deng, WJ Box, LC Condes, Y Okamoto… - Journal of Membrane …, 2022 - Elsevier
While the role of fluorine on mass transport in polymers has been the subject of extensive
research efforts, less attention has been paid to the role played by other halogens, such as …

Elucidating the Molecular Mechanisms by which Porous Polymer Networks Affect Structure, Aging Propensity, and Selectivity of Microporous Glassy Polymer …

LC Condes, MT Webb, TTB Le, WJ Box… - … Applied Materials & …, 2024 - ACS Publications
Microporous glassy polymer membranes suffer from physical aging, which adversely affects
their performance in the short time frame. We show that the aging propensity of a model …

Computer vision-based measurement of pure-and mixed-gas swelling in polymer membranes: Individual and synergistic effects of configurational free volume and …

WJ Box, LC Condes, MT Webb, A Suleiman… - Journal of Membrane …, 2024 - Elsevier
Although polymer swelling (ie, dilation) data are crucial to assess the long-term stability of
polymer membranes and correct sorption isotherms for highly sorbing penetrants, the …

Polymer Morphological Effect on Gas Transport within Triptycene-Based Polysulfones

T Corrado, T Wang, Z Huang, J Aboki… - ACS Applied Polymer …, 2021 - ACS Publications
In this study, the effect of polymer morphology on chain packing and physical and gas
transport properties was explored via the creation and study of three polysulfone copolymer …

[图书][B] Development of Iptycene-Containing Polysulfones And Ladder Polymers for Gas Separation Membranes

TJ Corrado - 2022 - search.proquest.com
Conventional separation methods such as sorption processes and cryogenic distillation are
extremely energy intensive, and membrane technology is especially attractive as an …

[引用][C] ADVANCING POLYMER MEMBRANES THROUGH CONFIGURATIONAL FREE VOLUME AND MEASUREMENT INNOVATIONS

W Box - 2024