A review of the biotechnological production of methacrylic acid

J Lebeau, JP Efromson, MD Lynch - Frontiers in Bioengineering and …, 2020 - frontiersin.org
Industrial biotechnology can lead to new routes and potentially to more sustainable
production of numerous chemicals. We review the potential of biobased routes from sugars …

C4 hydrocarbons to value-added chemicals over Keggin-type heteropolyacids: structure-properties, reaction parameters, and mechanisms

X Zhang, W Lin, LQ Lau, CL Ngan, SY Lai - Brazilian Journal of Chemical …, 2024 - Springer
Decades of heavy reliance on petroleum refineries for energy have led to perpetual
environmental pollution. These emissions include sulfur oxides, nitrogen oxides, carbon …

Cooperative catalytic effects between Brønsted and Lewis acid sites and kinetics for production of methyl methacrylate on SO42−/TiO2-SiO2

G Wang, G Cai - Chemical Engineering Science, 2021 - Elsevier
Either the ethylene or isobutene-based route for industrial production of methyl methacrylate
(MMA) contains the esterification step between methacrylic acid (MAA) and methanol …

Single-Step Production of Bio-Based Methyl Methacrylate from Biomass-Derived Organic Acids Using Solid Catalyst Material for Cascade Decarboxylation …

A Bohre, K Avasthi, U Novak… - … Sustainable Chemistry & …, 2021 - ACS Publications
This study shows the direct chemical conversion of a widely available carbohydrate-derived
itaconic acid/methanol into the methyl methacrylate (MMA) ester via cascade …

Efficient bio-production of citramalate using an engineered Escherichia coli strain

JP Webb, SA Arnold, S Baxter, SJ Hall… - …, 2018 - microbiologyresearch.org
Citramalic acid is a central intermediate in a combined biocatalytic and chemocatalytic route
to produce bio-based methylmethacrylate, the monomer used to manufacture Perspex and …

Esterification of methacrylic acid with methanol: Process optimization, kinetic modeling, and reactive distillation

R Ran, J Li, G Wang, Z Li, C Li - Industrial & Engineering …, 2019 - ACS Publications
The esterification of methacrylic acid with methanol catalyzed by NKC-9 resin (a cation-
exchange resin with sulfonate groups) was conducted in a stainless stirred batch reactor …

A new route for the synthesis of methacrylic acid from 2-methyl-1, 3-propanediol by integrating biotransformation and catalytic dehydration

SH Pyo, T Dishisha, S Dayankac, J Gerelsaikhan… - Green …, 2012 - pubs.rsc.org
Methacrylic acid was produced in high yield by an integrated process involving
bioconversion of 2-methyl-1, 3-propanediol (2M1, 3PD) to 3-hydroxy-2-methylpropionic acid …

Novel eco-efficient process for methyl methacrylate production

MD Moraru, CS Bildea, AA Kiss - Industrial & Engineering …, 2021 - ACS Publications
Methyl methacrylate is an essential chemical used as raw material for the production of other
methacrylates and poly-methyl methacrylate. There are various chemistry routes, available …

Zeolite Y hydrolyses methyl methacrylate to methacrylic acid in the gas phase

OV Chub, JL Dubois, GS Patience - Chemical Engineering Journal, 2023 - Elsevier
Abstract Poly (methyl methacrylate)(PMMA) depolymerizes to its monomer methyl
methacrylate (MMA) below 400° C but the accompanying byproducts have similar boiling …

[图书][B] Microbial production of bio-based chemicals: a biorefinery perspective

T Dishisha - 2013 - lup.lub.lu.se
A shift from fossil-to renewable biomass feedstock for the emerging bio-based economy
requires the development and adoption of new sustainable technologies that are more …