Synthesis of conjugated polymers for organic solar cell applications

YJ Cheng, SH Yang, CS Hsu - Chemical reviews, 2009 - ACS Publications
Harvesting energy directly from sunlight using photovoltaic technology is considered as
being one of the most important ways to address growing global energy needs using a …

Synthetic principles for bandgap control in linear π-conjugated systems

J Roncali - Chemical reviews, 1997 - ACS Publications
The electronic properties of linear π-conjugated systems (LCSs) have acquired a growing
importance in many areas of modern chemistry and physics of condensed matter. At the …

50th Anniversary Perspective: Conducting/Semiconducting Conjugated Polymers. A Personal Perspective on the Past and the Future

TM Swager - Macromolecules, 2017 - ACS Publications
It has been about 40 years since the field of organic conducting polymers was ignited by the
demonstration of metallic conductivity in polyacetylene. A retrospective view of this research …

Design of Narrow-Bandgap Polymers. Syntheses and Properties of Monomers and Polymers Containing Aromatic-Donor and o-Quinoid-Acceptor Units

C Kitamura, S Tanaka, Y Yamashita - Chemistry of Materials, 1996 - ACS Publications
A series of novel monomers and polymers containing aromatic-donor and o-quinoid-
acceptor units was prepared, and the relationship between their spectral and …

2, 1, 3‐Benzothiadiazole and derivatives: synthesis, properties, reactions, and applications in light technology of small molecules

BAD Neto, AAM Lapis… - European Journal of …, 2013 - Wiley Online Library
Abstract 2, 1, 3‐Benzothiadiazole (BTD) is one of the most important nuclei used in the
chemistry of photoluminescent compounds and applicable for light technology. The …

Fused electron deficient semiconducting polymers for air stable electron transport

A Onwubiko, W Yue, C Jellett, M Xiao, HY Chen… - Nature …, 2018 - nature.com
Conventional semiconducting polymer synthesis typically involves transition metal-mediated
coupling reactions that link aromatic units with single bonds along the backbone. Rotation …

A quantum-chemical perspective into low optical-gap polymers for highly-efficient organic solar cells

C Risko, MD McGehee, JL Brédas - Chemical Science, 2011 - pubs.rsc.org
The recent and rapid enhancement in power conversion efficiencies of organic-based, bulk-
heterojunction solar cells has been a consequence of both improved materials design and …

A spray-processable, low bandgap, and ambipolar donor− acceptor conjugated polymer

TT Steckler, X Zhang, J Hwang… - Journal of the …, 2009 - ACS Publications
Combining a strong donor, tris (dodecyloxy) phenyl)-dithieno [3, 2-b: 2′, 3′-d] pyrrole, with
a strong acceptor, 4, 8-dithien-2-yl-2λ4δ2-benzo [1, 2-c; 4, 5-c′] bis [1, 2, 5] thiadiazole, has …

Extensive quinoidal oligothiophenes with dicyanomethylene groups at terminal positions as highly amphoteric redox molecules

T Takahashi, K Matsuoka, K Takimiya… - Journal of the …, 2005 - ACS Publications
A series of highly extensive quinoidal oligothiophenes carrying a dicyanomethylene group
at both terminal positions is synthesized. As the quinoidal structures extend, they have …

Quinoidal conjugated polymers with open-shell character

X Ji, L Fang - Polymer Chemistry, 2021 - pubs.rsc.org
π-Conjugated polymers composed of quinoidal or proquinoidal building blocks represent an
intriguing class of macromolecules in terms of both fundamental research and practical …