Chiral supramolecular polymers

F García, R Gómez, L Sánchez - Chemical Society Reviews, 2023 - pubs.rsc.org
As an active branch within the field of supramolecular polymers, chiral supramolecular
polymers (SPs) are an excellent benchmark to generate helical structures that can clarify the …

Self-assembled stereomutation with supramolecular chirality inversion

G Liu, MG Humphrey, C Zhang, Y Zhao - Chemical Society Reviews, 2023 - pubs.rsc.org
Supramolecular chirality is involved not only in biological events such as gene
communication, replication, and enzyme catalysis but also in artificial self-assembly systems …

Supramolecular chiroptical switches

L Zhang, HX Wang, S Li, M Liu - Chemical Society Reviews, 2020 - pubs.rsc.org
Chiroptical switches, whose chiral optical signals such as optical rotatory dispersion (ORD),
circular dichroism (CD) and circularly polarized luminescence (CPL) are reversibly …

Multiple hydrogen bonding driven supramolecular architectures and their biomedical applications

Y Liu, L Wang, L Zhao, Y Zhang, ZT Li… - Chemical Society …, 2024 - pubs.rsc.org
Supramolecular chemistry combines the strength of molecular assembly via various
molecular interactions. Hydrogen bonding facilitated self-assembly with the advantages of …

Supramolecular helical systems: helical assemblies of small molecules, foldamers, and polymers with chiral amplification and their functions

E Yashima, N Ousaka, D Taura, K Shimomura… - Chemical …, 2016 - ACS Publications
In this review, we describe the recent advances in supramolecular helical assemblies
formed from chiral and achiral small molecules, oligomers (foldamers), and helical and …

Supramolecular chirality transfer toward chiral aggregation: asymmetric hierarchical self‐assembly

S Huang, H Yu, Q Li - Advanced Science, 2021 - Wiley Online Library
Self‐assembly, as a typical bottom‐up strategy for the fabrication of functional materials, has
been applied to fabricate chiral materials with subtle chiral nanostructures. The chiral …

Hierarchical self-assembly into chiral nanostructures

Y Sang, M Liu - Chemical Science, 2022 - pubs.rsc.org
One basic principle regulating self-assembly is associated with the asymmetry of constituent
building blocks or packing models. Using asymmetry to manipulate molecular-level devices …

Nonplanar porphyrins: synthesis, properties, and unique functionalities

T Ishizuka, N Grover, CJ Kingsbury, H Kotani… - Chemical Society …, 2022 - pubs.rsc.org
Porphyrins are variously substituted tetrapyrrolic macrocycles, with wide-ranging biological
and chemical applications derived from metal chelation in the core and the 18π aromatic …

[HTML][HTML] Stimuli-responsive synthetic helical polymers

M Lago-Silva, M Fernández-Míguez… - Chemical Society …, 2024 - pubs.rsc.org
Synthetic dynamic helical polymers (supramolecular and covalent) and foldamers share the
helix as a structural motif. Although the materials are different, these systems also share …

Stereochemical enhancement of polymer properties

JC Worch, H Prydderch, S Jimaja, P Bexis… - Nature Reviews …, 2019 - nature.com
The importance of stereochemistry to the function of molecules is generally well understood.
However, to date, control over stereochemistry and its potential to influence properties of the …