Chemical routes for the transformation of biomass into chemicals

A Corma, S Iborra, A Velty - Chemical reviews, 2007 - ACS Publications
Vegetable biomass is generated from CO2 and H2O using sunlight as the energy source,
producing O2 as a subproduct. The primary products formed are C6-and C5-sugars that …

Long-chain aliphatic polymers to bridge the gap between semicrystalline polyolefins and traditional polycondensates

F Stempfle, P Ortmann, S Mecking - Chemical reviews, 2016 - ACS Publications
Other than their established short-chain congeners, polycondensates based on long-chain
difunctional monomers are often dominated by the long methylene sequences of the repeat …

Ethenolysis: a green catalytic tool to cleave carbon–carbon double bonds

J Bidange, C Fischmeister… - Chemistry–A European …, 2016 - Wiley Online Library
Remarkable innovations have been made in the field of olefin metathesis due to the design
and preparation of new catalysts. Ethenolysis, which is cross‐metathesis with ethylene …

Drop-in biofuels production from microalgae to hydrocarbons: Microalgal cultivation and harvesting, conversion pathways, economics and prospects for aviation

S Martinez-Villarreal, A Breitenstein… - Biomass and …, 2022 - Elsevier
In the last few years, governments all around the world have agreed upon migrating towards
carbon-neutral economies as a strategy for restraining the effects of climate change. A major …

Bis (cyclic alkyl amino carbene) ruthenium complexes: a versatile, highly efficient tool for olefin metathesis

R Gawin, A Kozakiewicz, PA Guńka… - Angewandte …, 2017 - Wiley Online Library
The state‐of‐the‐art in olefin metathesis is application of N‐heterocyclic carbene (NHC)‐
containing ruthenium alkylidenes for the formation of internal C= C bonds and of cyclic alkyl …

Metathesis as a versatile tool in oleochemistry

A Rybak, PA Fokou, MAR Meier - European journal of lipid …, 2008 - Wiley Online Library
Olefin metathesis, awarded with the Nobel Prize in Chemistry 2005 for Chauvin, Grubbs and
Schrock, has emerged as a powerful tool for organic as well as polymer chemistry. In …

Room temperature ionic liquids as green solvent alternatives in the metathesis of oleochemical feedstocks

PA Thomas, BB Marvey - Molecules, 2016 - mdpi.com
One of the most important areas of green chemistry is the application of environmentally
friendly solvents in catalysis and synthesis. Conventional organic solvents pose a threat to …

High conversion and productive catalyst turnovers in cross-metathesis reactions of natural oils with 2-butene

J Patel, S Mujcinovic, WR Jackson, AJ Robinson… - Green …, 2006 - pubs.rsc.org
High conversion and selectivity can be obtained for the cross-metathesis of 2-butene with
triglycerides and unsaturated fatty acid esters derived from natural oils. This can be …

Development of a one-pot tandem reaction combining ruthenium-catalyzed alkene metathesis and enantioselective enzymatic oxidation to produce aryl epoxides

CA Denard, MJ Bartlett, Y Wang, L Lu, JF Hartwig… - ACS …, 2015 - ACS Publications
We report the development of a tandem chemoenzymatic transformation that combines
alkene metathesis with enzymatic epoxidation to provide aryl epoxides. The development of …

Continuous flow homogeneous alkene metathesis with built-in catalyst separation

R Duque, E Öchsner, H Clavier, F Caijo, SP Nolan… - Green chemistry, 2011 - pubs.rsc.org
Continuous flow homogeneous alkene metathesis using a supported ionic liquid phase
(SILP) catalyst with CO2 as a transport vector allows the self-metathesis of methyl oleate …