Pyrroloindolines are important and privileged polycyclic indoline motifs that are widely
present in natural products and bio-significant molecules. From an organic chemistry …

Polycyclic scaffolds are omnipresent in natural products and drugs, and the synthetic
strategies and methods toward construction of these scaffolds are of particular importance …

Herein we report a catalytic asymmetric dearomatization reaction of electron‐deficient
heteroarenes with α‐substituted isocyanoacetates through an interrupted Barton–Zard …

Indole-ynones have been established as general substrates for radical dearomatizing
spirocyclization cascade reactions. Five distinct and varied synthetic protocols have been …

Ag (I)-catalyzed highly diastereoselective construction of divergent spiroindolines is
disclosed herein. The approach proceeds via dearomatizing spirocyclization of indole …

Herein, we report a facile and efficient synthetic method to construct azepino [1, 2-a] indoles
through a novel gold (I)-catalyzed intramolecular hydroarylation of alkynylindoles. A wide …

Pd-catalyzed asymmetric dearomative arylation of C3-substituted indoles is realized via a
desymmetrization strategy. A BINOL-derived chiral phosphoramidite ligand is found to be …

The application of dinuclear zinc catalysts in a dearomatization reaction has been
developed. Catalytic asymmetric dearomatization [3+ 2] annulations of 2‐nitrobenzofurans …

A phosphine-catalyzed intermolecular asymmetric dearomatization reaction of
benzimidazoles with cyclopropenones has been developed. In the presence of 5 mol% of …

Herein, a novel cascade gold (I)-catalyzed hydroarylation of alkynylindoles and subsequent
Diels–Alder cycloaddition with electron-deficient alkynes and alkenes is described. A variety …