Radical species are significant in modern chemistry. Their unique chemical bonding and
novel physicochemical properties play significant roles not only in fundamental chemistry …

We present an approach for preparing chain-type unsaturated molecules with low oxidation
state Si (I) and Sb (I) supported by amidinato ligands that exploit to generate heavy …

A successful selective reduction of X2B-Tip (Tip= 1, 3, 5-i Pr3-C6H2, X= I, Br) with KC8 and
Mg metal, respectively, in the presence of a hybrid ligand (C6H4 (PPh2) LSi) leads to a …

Herein, we report the stabilization of lithium‐ion as the source of lithium to use as a trans‐
metalation reagent [{PhC (NtBu) 2Si (tBu) Li} 2I (tBuN) 2CPh](1). The reaction of 3 …

Herein we report the reduction of R‐EX2 (E= P, Sb) with two equivalents of KC8 in the
presence of silylene (LSiR; L= PhC (NtBu) 2) to give Trip‐P= SiL (C6H4PPh2)(1), TerPh …

Herein we report stable silicon-boron radicals of composition LSi (NMe2)–B (Br) Tip (1), LSi
(NMe2)–B (I) Tip (2) LSi (tBu)–B (I) Tip (3)[L= PhC (NtBu) 2]. They were prepared in high …

Herein, we report the isolation of pyridine moiety-functionalized SiNSi pincer-based bis-
silylene ligand (1) and its reactivity toward various halide precursors (X= Br and I) of group …

The inability of p‐block elements to participate in π‐backbonding restricts them from
activating small molecules like CO, H2, and so forth. However, the development of the main …

Herein, we report a one‐pot reaction of gallium and boron halides with potassium graphite
in the presence of benzamidinate stabilized silylene LSi‐R,(L= PhC (NtBu) 2). The reaction …

Stabilizing the exotic chemical species possessing multiple bonds is often extremely
challenging due to insufficient orbital overlap, especially involving one heavier element …