HFIP in organic synthesis

HF Motiwala, AM Armaly, JG Cacioppo… - Chemical …, 2022 - ACS Publications
1, 1, 1, 3, 3, 3-Hexafluoroisopropanol (HFIP) is a polar, strongly hydrogen bond-donating
solvent that has found numerous uses in organic synthesis due to its ability to stabilize ionic …

[HTML][HTML] Scholl reaction as a powerful tool for the synthesis of nanographenes: a systematic review

RS Jassas, EU Mughal, A Sadiq, RI Alsantali… - RSC …, 2021 - pubs.rsc.org
Nanographenes, or extended polycyclic aromatic hydrocarbons, have been attracting
increasing attention owing to their widespread applications in organic electronics. However …

Electrochemical Syntheses of Polycyclic Aromatic Hydrocarbons (PAHs)

Y Wang, R Zhao, L Ackermann - Advanced Materials, 2023 - Wiley Online Library
Polycyclic aromatic hydrocarbons (PAHs) have surfaced as increasingly viable components
in optoelectronics and material sciences. The development of highly efficient and atom …

Rearrangements in Scholl reaction

N Ponugoti, V Parthasarathy - Chemistry–A European Journal, 2022 - Wiley Online Library
Rearrangements in Scholl reaction are mostly serendipitous. The design of molecular
precursors is what seems to guide the course of rearrangement. This review consolidates …

Get into flow: Design of experiments as a key technique in the optimization of anodic dehydrogenative C, C cross-coupling reaction of phenols in flow electrolyzers

MM Hielscher, B Gleede, SR Waldvogel - Electrochimica Acta, 2021 - Elsevier
The optimization of electro-organic reactions poses a challenge due to the various
parameters involved. Quite often those parameters are not independent from each other …

Straightforward electrochemical sulfonylation of arenes and aniline derivatives using sodium sulfinates

J Nikl, D Ravelli, D Schollmeyer… - …, 2019 - Wiley Online Library
We present a general electrochemical synthesis of sulfones from arenes and aniline
derivatives with sodium sulfinates. A wide range of C− S cross‐coupling products is …

S-shaped fused azacorannulene dimer: structural and redox properties

W Wang, F Hanindita, RD Webster, S Ito - CCS Chemistry, 2023 - chinesechemsoc.org
Because of their unique structural and chemical properties, buckybowl molecules have
attracted considerable attention in a wide range of scientific disciplines. The importance and …

Electrochemical Continuous-Flow Scholl Reaction toward Polycyclic Aromatic Hydrocarbons

WZ Wang, Q Wang, X He, YH Shen, Z Zhai… - Organic …, 2024 - ACS Publications
The preparation of polycyclic aromatic hydrocarbons (PAHs) by the Scholl reaction is
typically performed by using superstoichiometric oxidants. Herein, we develop an …

[HTML][HTML] About the selectivity and reactivity of active nickel electrodes in C–C coupling reactions

SB Beil, M Breiner, L Schulz, A Schüll, T Müller… - RSC …, 2020 - pubs.rsc.org
Active anodes which are operating in highly stable protic media such as 1, 1, 1, 3, 3, 3-
hexafluoroisopropanol are rare. Nickel forms, within this unique solvent, a non-sacrificial …

Staggarenes-A New Family of Extended Aromatic Systems Based on Fused Anthracenes

F Alkahtani - 2024 - ueaeprints.uea.ac.uk
The overall objective of this project is to synthesise and design unique new extended
aromatic structures assembling fundamental three-ring aromatic units (anthracenes) …