Electrocatalysis in alkaline media and alkaline membrane-based energy technologies

Y Yang, CR Peltier, R Zeng, R Schimmenti, Q Li… - Chemical …, 2022 - ACS Publications
Hydrogen energy-based electrochemical energy conversion technologies offer the promise
of enabling a transition of the global energy landscape from fossil fuels to renewable energy …

Progress and Perspectives of Electrochemical CO2 Reduction on Copper in Aqueous Electrolyte

S Nitopi, E Bertheussen, SB Scott, X Liu… - Chemical …, 2019 - ACS Publications
To date, copper is the only heterogeneous catalyst that has shown a propensity to produce
valuable hydrocarbons and alcohols, such as ethylene and ethanol, from electrochemical …

Beyond extended surfaces: understanding the oxygen reduction reaction on nanocatalysts

Z Liu, Z Zhao, B Peng, X Duan… - Journal of the American …, 2020 - ACS Publications
Increasing the platinum utilization efficiency is the key to the advancement and broad
dissemination of proton-exchange-membrane fuel cells (PEMFCs). Central to the task is the …

Operando Electron Microscopy of Catalysts: The Missing Cornerstone in Heterogeneous Catalysis Research?

SW Chee, T Lunkenbein, R Schlögl… - Chemical …, 2023 - ACS Publications
Heterogeneous catalysis in thermal gas-phase and electrochemical liquid-phase chemical
conversion plays an important role in our modern energy landscape. However, many of the …

Nanoscale surface structure–activity in electrochemistry and electrocatalysis

CL Bentley, M Kang, PR Unwin - Journal of the American …, 2018 - ACS Publications
Nanostructured electrochemical interfaces (electrodes) are found in diverse applications
ranging from electrocatalysis and energy storage to biomedical and environmental sensing …

Electrochemical activation of single-walled carbon nanotubes with pseudo-atomic-scale platinum for the hydrogen evolution reaction

M Tavakkoli, N Holmberg, R Kronberg, H Jiang… - Acs …, 2017 - ACS Publications
The development of effective and inexpensive hydrogen evolution reaction (HER)
electrocatalysts for future renewable energy systems is highly desired. Platinum-based …

Electric double layer effects in electrocatalysis: Insights from ab initio simulation and hierarchical continuum modeling

P Li, Y Jiao, J Huang, S Chen - JACS Au, 2023 - ACS Publications
Structures of the electric double layer (EDL) at electrocatalytic interfaces, which are
modulated by the material properties, the electrolyte characteristics (eg, the pH, the types …

Structure dependency of the atomic-scale mechanisms of platinum electro-oxidation and dissolution

T Fuchs, J Drnec, F Calle-Vallejo, N Stubb… - Nature Catalysis, 2020 - nature.com
Platinum dissolution and restructuring due to surface oxidation are primary degradation
mechanisms that limit the lifetime of platinum-based electrocatalysts for electrochemical …

Single entity electrocatalysis

TB Clarke, LE Krushinski, KJ Vannoy… - Chemical …, 2024 - ACS Publications
Making a measurement over millions of nanoparticles or exposed crystal facets seldom
reports on reactivity of a single nanoparticle or facet, which may depart drastically from …

Why conclusions from platinum model surfaces do not necessarily lead to enhanced nanoparticle catalysts for the oxygen reduction reaction

F Calle-Vallejo, MD Pohl, D Reinisch, D Loffreda… - Chemical …, 2017 - pubs.rsc.org
Experiments on model surfaces commonly help in identifying the structural sensitivity of
catalytic reactions. Nevertheless, their conclusions do not frequently lead to devising …