Effect of Polyelectrolyte Charge Density on the Linear Viscoelastic Behavior and Processing of Complex Coacervate Adhesives

L van Westerveld, T Pelras, AH Hofman, K Loos… - …, 2024 - ACS Publications
It is well-known that the phase behavior and physicochemical and adhesive properties of
complex coacervates are readily tuneable with the salt concentration of the medium. For …

Coacervating behavior of amino acid anionic and amphoteric mixed micelle-polymer

F Wang, W Feng, Z Zhu, J Zhang, H Wei, L Dang - Soft Matter, 2024 - pubs.rsc.org
In this paper, coacervates were formed with mixed micelles consisting of the anionic amino
acid surfactant sodium lauroylsarcosinate (NLS) and amphoteric surfactant cocamidopropyl …

Decoupling the Effects of Charge Density and Hydrophobicity on the Phase Behavior and Viscoelasticity of Complex Coacervates

IA Ramírez Marrero, L Boudreau, W Hu… - …, 2024 - ACS Publications
Here, we explore the effect of copolymer chemistry on the phase behavior and viscoelasticity
of complex coacervates. To this end, we utilized a library of methacrylate copolymers with …

Influence of counterions on the thermal and solution properties of strong polyelectrolytes

T Pelras, JE Sayed, J Pierik, A Giuntoli… - Polymer …, 2025 - pubs.rsc.org
Strong polyelectrolytes (ie, macromolecules whose charge density is independent of the
medium's pH) are invaluable assets in the soft matter toolbox, as they can readily disperse in …

Lipidation alters the phase-separation of resilin-like polypeptides

Z Zhang, J Ji, MS Hossain, B Bailey, S Nangia… - Soft Matter, 2024 - pubs.rsc.org
Biology exploits biomacromolecular phase separation to form condensates, known as
membraneless organelles. Despite significant advancements in deciphering sequence …

Effect of Cation-π Interactions on the Phase Behavior and Viscoelastic Properties of Polyelectrolyte Complexes

C Chee, A Han, G Ortiz, L Knight, J Laaser - 2024 - chemrxiv.org
Aromatic rings are a common feature of biological and synthetic polymers that form
polyelectrolyte complexes and coacervates. These functional groups can engage in cation-π …