MOFs as proton conductors–challenges and opportunities

P Ramaswamy, NE Wong, GKH Shimizu - Chemical Society Reviews, 2014 - pubs.rsc.org
Proton conducting materials have garnered immense attention for their role as electrolytes in
fuel cells. Metal Organic Frameworks (MOFs) and coordination polymers have recently been …

Proton conductive metal phosphonate frameworks

SS Bao, GKH Shimizu, LM Zheng - Coordination Chemistry Reviews, 2019 - Elsevier
This review covers basic design principles and offers a cross-section of the current status of
phosphonate MOFs as proton conductors. Metal phosphonates are often sustained by …

Metal phosphonate chemistry

A Clearfield - Progress in inorganic chemistry, 1998 - books.google.com
Metal phosphonate chemistry Page 381 Metal Phosphonate Chemistry ABRAHAM
CLEARFIELD Texas A&M University College Station, TX CONTENTS I. lntmduction II. Zirconium …

Tuning intrinsic and extrinsic proton conduction in metal–organic frameworks by the lanthanide contraction

NE Wong, P Ramaswamy, AS Lee… - Journal of the …, 2017 - ACS Publications
Seven isomorphous lanthanide metal–organic frameworks in the PCMOF-5 family,[Ln
(H5L)(H2O) n](H2O)(L= 1, 2, 4, 5-tetrakis (phosphonomethyl) benzene, Ln= La, Ce, Pr, Nd …

Co–Ca phosphonate showing humidity-sensitive single crystal to single crystal structural transformation and tunable proton conduction properties

SS Bao, NZ Li, JM Taylor, Y Shen… - Chemistry of …, 2015 - ACS Publications
A combination of humidity-dependent single crystal to single crystal (SC–SC) structural
transformation and single crystal proton conductivity measurements is essential to elucidate …

Conductive metal–organic frameworks: Mechanisms, design strategies and recent advances

X Deng, JY Hu, J Luo, WM Liao, J He - Topics in Current Chemistry, 2020 - Springer
Abstract Metal–organic frameworks (MOFs), constructed from metal ions and organic ligands
through coordination assembly, exhibit considerable conductivity, which originates from the …

Enhancing Proton Conduction in 2D Co–La Coordination Frameworks by Solid-State Phase Transition

SS Bao, K Otsubo, JM Taylor, Z Jiang… - Journal of the …, 2014 - ACS Publications
We report that a new 2D 3d–4f phosphonate [CoIIILaIII (notpH)(H2O) 6] ClO4· 5H2O (CoLa-
II) can undergo a phase transition above 45° C and 93% relative humidity, resulting in …

Structural chemistry of uranium phosphonates

W Yang, TG Parker, ZM Sun - Coordination Chemistry Reviews, 2015 - Elsevier
Uranium phosphonates, an important class of actinide-organic coordination polymers,
exhibit an exceptionally diverse and broad range of crystal structures. A variety of structure …

A multifunctional porous uranyl phosphonate framework for cyclic utilization: salvages, uranyl leaking prevention, and fluorescent sensing

H Zhao, C Qi, X Yan, J Ji, Z Chai, S Wang… - ACS Applied Materials …, 2022 - ACS Publications
The material for managing and monitoring waste made from the waste itself is an excellent
example of cyclic utilization, which could reduce issues and be more sustainable. A three …

MOFs of Uranium and the Actinides

J Su, J Chen - Lanthanide Metal-Organic Frameworks, 2015 - Springer
Although the transition d-or 4f-block elements are the most used metals for the construction
of metal–organic frameworks (MOFs), actinide cations were also involved in the elaboration …