Monoligated palladium (0) species, L1Pd (0), have emerged as the most active catalytic
species in the cross-coupling cycle. Today, there are methods available to generate the …

The story of C− C bond formation includes several reactions, and surely Suzuki‐Miyaura is
among the most outstanding ones. Herein, a brief historical overview of insights regarding …

Methods to functionalize arenes and heteroarenes in a site-selective manner are highly
sought after for rapidly constructing value-added molecules of medicinal, agrochemical, and …

Palladium-catalysed processes for the formation of carbon–carbon bonds, ie, coupling
reactions of organic halides (R1X) and main-group organometallic compounds (R2M) are …

The strong electron-donation and the steric bulk of trialkylphosphines renders them as very
useful ligands for palladium-catalyzed cross coupling reactions. This critical review reports …

Detailed kinetic studies of the reaction of a model Ni0 complex with a range of aryl
electrophiles have been conducted. The reactions proceed via a fast ligand exchange pre …

The first Suzuki− Miyaura cross-coupling reactions of the synthetically versatile aryl O-
carbamate and O-sulfamate groups are described. The transformations utilize the …

The reversal of regioselectivity in a Pd-catalyzed cross-coupling reaction of an aryl chloro
triflate with different ligands, established by Fu and co-workers, has been studied …

The oxidative addition (OA) of organic electrophiles to Pd (0) is a fundamental step in
organopalladium chemistry and plays a key role in palladium-catalyzed cross-coupling …

The oxidative addition of PhX (X= I, Br, Cl) to the complexes Pd (P t Bu3) 2 (1), Pd (1-AdP t
Bu2) 2 (2), Pd (CyP t Bu2) 2 (3), and Pd (PCy3) 2 (4)(1-Ad= 1-adamantyl, Cy= cyclohexyl) …