Conspectus Catalytic atroposelective syntheses of axially chiral compounds have stimulated
extensive interest in multiple communities, such as synthetic chemistry, biochemistry, and …

Synthetic organic electrosynthesis has grown in the past few decades by achieving many
valuable transformations for synthetic chemists. Although electrocatalysis has been popular …

Atropisomerism is a stereochemical behavior portrayed by three-dimensional molecules that
bear rotationally restricted σ bond. Akin to the well-represented point-chiral molecules …

Transition-metal-catalyzed enantioselective C–H functionalization has become a powerful
strategy for the formation of C–C or C–X bonds, enabling the highly asymmetric synthesis of …

The first highly atroposelective construction of N− N axially chiral indole scaffolds was
established via a new strategy of de novo ring formation. This strategy makes use of the …

Transition metal‐catalyzed enantioselective functionalization of C− H bond, the most
abundant functionality in organic molecules, has emerged as an expedient synthetic …

Direct catalytic transformation of C–H bonds to new functionalities has provided a powerful
strategy to synthesize complex molecular scaffolds in a straightforward way. Unstinting …

Axial chirality widely exists in natural products, pharmaceutical compounds, and other
functional molecules; these axially chiral compounds also find wide utility as catalysts or …

Ru (II)-catalyzed enantioselective C–H functionalization involving an enantiodetermining C–
H cleavage step remains undeveloped. Here we describe a Ru (II)-catalyzed …

The atroposelective synthesis of atropisomers with vicinal diaxes remains rare and
challenging, due to the steric influence between the two axes and their unique topology …