Despite the rich chemistry of palladium in oxidation states of 0,+ 2, and+ 4, no PdIII
coordination compounds have been reported until the 1980s. Moreover, while Pd …

Transformations involving Pd (I) and Pd (III) have received growing attention over the past
few years, providing various methodologies for the construction of numerous carbocyclic …

While palladium catalysis is ubiquitous in modern chemical research, the recovery of the
active transition‐metal complex under routine laboratory applications is frequently …

This review article features recent progress in the field of metal-metal bonding chemistry,
with a focus on Li-Li, Be-Be, and Mg-Mg bonds via computational means. The use of …

Catalytic transformations involving Pd (0)/Pd (II) catalytic cycles are very well known, and
processes involving high-valent Pd (III) and Pd (IV) and low-valent Pd (I) intermediates have …

The chemical and electrochemical one-electron oxidation of [Pd (IPr) 2](1) leads to the
formation of mononuclear palladium (I) complex [Pd (IPr) 2][PF6](2). This bench-stable …

Oxidation of the PdII complex (N4) PdIIMe2 (N4= N, N′-di-tert-butyl-2, 11-diaza [3.3](2, 6)
pyridinophane) with O2 or ROOH (R= H, tert-butyl, cumyl) produces the PdIII species [(N4) …

A mononuclear, T‐shaped palladium (I) d9 metalloradical (3), stabilized by a bulky
carbazole‐based PNP‐ligand, was obtained by reduction of palladium chloride or thermal …

This report provides experimental, computational and spectroscopic data in support of the
direct reactivity of a Pd (I) dimer with an aryl iodide, resulting in Br/I halogen exchange …

Abstract Knowledge of exactly how metal complexes react with molecular oxygen is still
limited and this has hampered efforts to develop catalysts for oxidation reactions using O2 …