Lanthanide complexes as chiral probes exploiting circularly polarized luminescence

R Carr, NH Evans, D Parker - Chemical Society Reviews, 2012 - pubs.rsc.org
Optical probes that provide information about local chirality have been developed based on
changes to the circular polarisation of emitted light. Highly emissive complexes of lanthanide …

Chiral lanthanide complexes: coordination chemistry and applications

HC Aspinall - Chemical reviews, 2002 - ACS Publications
The classical examples of chirality in coordination chemistry are transition-metal chelate
complexes of the type [M (bidentate) 3] that exist in nonsuperimposable mirror image forms …

Beyond chiral organic (p-block) chromophores for circularly polarized luminescence: the success of d-block and f-block chiral complexes

B Doistau, JR Jiménez, C Piguet - Frontiers in chemistry, 2020 - frontiersin.org
Chiral molecules are essential for the development of advanced technological applications
in spintronic and photonic. The best systems should produce large circularly polarized …

Carboxylates of rare earth elements

R Janicki, A Mondry, P Starynowicz - Coordination Chemistry Reviews, 2017 - Elsevier
Rare earth carboxylates constitute an enormous group of compounds with various structures
and properties. The carboxylate group may be bonded to the metal cations in several ways …

Influence of dipicolinate ligands on the spectroscopic properties of europium (III) in solution

K Binnemans, K Van Herck, C Görller-Walrand - Chemical Physics Letters, 1997 - Elsevier
Absorption spectra of complexes between Eu3+ and the dipicolinate (2, 6-
pyridinedicarboxylate) ligand are recorded for several metal-to-ligand ratios. The influence …

Near-infrared luminescence of lanthanide calcein and lanthanide dipicolinate complexes doped into a silica− PEG hybrid material

K Driesen, R Van Deun, C Görller-Walrand… - Chemistry of …, 2004 - ACS Publications
The near-infrared luminescence of lanthanide complexes of 4 ', 5 '-bis [N, N-bis
(carboxymethyl) aminomethyl] fluorescein (calcein) and pyridine-2, 6-dicarboxylic acid …

Survey of factors determining the circularly polarised luminescence of macrocyclic lanthanide complexes in solution

JI Bruce, D Parker, S Lopinski… - … of Molecular Asymmetry, 2002 - Wiley Online Library
The development of emissive lanthanide complexes as structural or reactive probes to
signal changes in their local chiral or ionic environment has been inhibited by the lack of …

Circularly polarized luminescence spectroscopy from lanthanide systems

JP Riehl, G Muller - Handbook on the physics and chemistry of …, 2005 - books.google.com
The very first report of the detection of circular polarization in the emission of a chiral
molecular system was by Samoilov in 1948 who was studying crystals of sodium uranyl …

Paramagnetic DOSY: an accurate tool for the analysis of the supramolecular interactions between lanthanide complexes and proteins

S Denis‐Quanquin, F Riobé, MA Delsuc… - … A European Journal, 2016 - Wiley Online Library
Diffusion ordered NMR is implemented to determine accurately the mobility of paramagnetic
tris‐dipicolinate lanthanide complexes that are versatile probes of protein structure. It is …

Chiral discrimination in electronic energy-transfer processes between dissymmetric metal complexes in solution. Time-resolved chiroptical luminescence …

DH Metcalf, SW Snyder, JN Demas… - Journal of the …, 1990 - ACS Publications
Steady-state and time-resolved chiroptical luminescence measurements are used
toinvestigate enantioselective excited-state quenching processes in solution. Theory and …