Solid-state molecular organometallic chemistry. Single-crystal to single-crystal reactivity and catalysis with light hydrocarbon substrates

FM Chadwick, AI McKay, AJ Martinez-Martinez… - Chemical …, 2017 - pubs.rsc.org
Single-crystal to single-crystal solid/gas reactivity and catalysis starting from the precursor
sigma-alkane complex [Rh (Cy2PCH2CH2PCy2)(η2η2-NBA)][BArF4](NBA= norbornane; …

Metal–organic frameworks with hexakis (4-carboxyphenyl) benzene: Extensions to reticular chemistry and introducing foldable nets

FM Amombo Noa, E Svensson Grape… - Journal of the …, 2020 - ACS Publications
Nine metal–organic frameworks have been prepared with the hexagon-shaped linker 1, 2, 3,
4, 5, 6-hexakis (4-carboxyphenyl) benzene (H6cpb) by solvothermal reactions in …

The synthesis, structure, topology and catalytic application of a novel cubane-based copper (II) metal–organic framework derived from a flexible amido tripodal acid

A Karmakar, CL Oliver, S Roy, L Öhrström - Dalton Transactions, 2015 - pubs.rsc.org
A novel chiral metal–organic framework,[Cu4 (HL) 2 (H2O) 4 (MeO) 4] n (1), has been
successfully synthesized from a tripodal flexible ligand (2S, 2′ S, 2′′ S)-2, 2′, 2 …

Pyrazole-based PCN pincer complexes of palladium (II): Mono-and dinuclear hydroxide complexes and ligand rollover C–H activation

WD Bailey, L Luconi, A Rossin, D Yakhvarov… - …, 2015 - ACS Publications
Palladium complexes of the novel unsymmetrical phosphine pyrazole-containing pincer
ligands PCNH (PCNH= 1-[3-[(di-tert-butylphosphino) methyl] phenyl]-1 H-pyrazole) and …

Which Type of Pincer Complex Is Thermodynamically More Stable? Understanding the Structures and Relative Bond Strengths of Group 10 Metal Complexes …

F Fang, JX Kang, CQ Xu, J Chang, J Zhang… - Inorganic …, 2021 - ACS Publications
The influence of the pincer platform composition and substitution on the reactivity and
physical properties of pincer complexes can be easily explored through different …

Aromatic PCN palladium pincer complexes. Probing the hemilability through reactions with nucleophiles

A Fleckhaus, AH Mousa, NS Lawal… - …, 2015 - ACS Publications
A series of unsymmetrical PCN pincer ligands (1-(3-((di-tert-butylphosphino) methyl) phenyl)-
N, N-dialkylmethanamine) were cyclometalated with palladium to generate a series of new …

Designing, describing and disseminating new materials by using the network topology approach

L Öhrström - Chemistry–A European Journal, 2016 - Wiley Online Library
This Concept article describes how network topology analysis is applied to different fields of
solid‐state chemistry. Its usefulness is demonstrated by examples from metal–organic …

Influence of the Leaving Group on C–H Activation Pathways in Palladium Pincer Complexes

MR Hoffbauer, CC Comanescu, BJ Dymm… - Organometallics, 2018 - ACS Publications
A series of palladium pincer complexes supported by (i Pr2P-C6H4) 2CH2 (PC (sp3) H2P=
bis (2-(diisopropylphosphanyl) phenyl) methane) was isolated and characterized. Different …

Diastereomerization Dynamics of a Bistridentate RuII Complex

M Jarenmark, G Carlström, LA Fredin… - Inorganic …, 2016 - ACS Publications
The unsymmetrical nature of a new tridentate ligand bis (quinolinyl)-1, 3-pyrazole (DQPz) is
exploited in a bistridentate Ru (II) complex [Ru (DQPz) 2] 2+ to elucidate an unexpected …

Halide exchange studies of novel Pd (ii) NNN-pincer complexes

S Kuyuldar, C Burda, WB Connick - RSC advances, 2019 - pubs.rsc.org
Palladium (II) complexes with an NNN type pincer ligand (pip2NNN= 2, 6-bis (piperdyl-
methyl) pyridine) are synthesized and characterized. Electronic and 1H NMR spectra point …