Enantiomerically pure cyclobutane derivatives and their use in organic synthesis

E Lee-Ruff, G Mladenova - Chemical reviews, 2003 - ACS Publications
Although cyclobutanes have been known for more than a century, their use as synthetic
intermediates has only flourished in the last 30 years. Their diversity of reactions is the result …

Metal-assisted cycloaddition reactions in organotransition metal chemistry

HW Frühauf - Chemical reviews, 1997 - ACS Publications
Cycloaddition reactions in organic chemistry are not only among the synthetically most
useful reactions, they are also among the theoretically and mechanistically best understood …

Fischer carbene complexes in organic synthesis: metal-assisted and metal-templated reactions

KH Doetz, J Stendel Jr - Chemical reviews, 2009 - ACS Publications
The formal combination of a carbene and an organometallic fragment yields carbene
complexes. They are commonly classified as Fischer-and Schrock-type complexes. While …

[图书][B] Carbene chemistry: from fleeting intermediates to powerful reagents

G Bertrand - 2002 - api.taylorfrancis.com
Carbene Chemistry Page 1 Page 2 Carbene Chemistry FROM FLEETING
INTERMEDIATES TO POWERFUL REAGENTS Edited by Guy Bertrand Page 3 ISBN 0-203-91092-3 …

Carbene− alkyne− alkene cyclization reactions

DF Harvey, DM Sigano - Chemical reviews, 1996 - ACS Publications
Over the last several decades, our understanding of the reactivity of organotransition metal
complexes has improved tremendously. Many organotransitionmetal-based processes are …

Total Synthesis of the Hexacyclic Sesterterpenoid Niduterpenoid B via Structural Reorganization Strategy

Y Xue, SH Hou, X Zhang, FM Zhang… - Journal of the …, 2024 - ACS Publications
To date, it remains challenging to precisely and efficiently construct structurally intriguing
polycarbocycles with densely packed stereocenters in organic synthesis. Niduterpenoid B, a …

Chromium carbene complex photochemistry in organic synthesis

LS Hegedus - Tetrahedron, 1997 - Elsevier
I. Introduction 2. Reactions 2.1, Cycloaddition reactions 2.1. a With imines to give [3-1actams
2.1. b With olefins to give cyclobutanones 2.1. c With azoarenes 2.1. d With aldehydes to …

A contribution to the confusion surrounding the reaction of ketenes with imines to produce. beta.-lactams. A comparison of stereoselectivity dependence on the method …

LS Hegedus, J Montgomery, Y Narukawa… - Journal of the …, 1991 - ACS Publications
The stereoselectivity of the reaction of imines of benzaldehyde and cinnamaldehyde with
ketenes generated by the reaction of optically active oxazolidinone acid chlorides with …

Synthesis of amino acids and peptides using chromium carbene complex photochemistry

LS Hegedus - Accounts of chemical research, 1995 - ACS Publications
Amino acids are a biologically significant class of compounds, since they are the basic
building blocks for peptides and proteins, the biopolymers responsible for both the structure …

(1-Alkynyl) carbene Complexes (= 1-Metalla-1-buten-3-ynes): Tools for Synthesis

R Aumann, H Nienaber - Advances in Organometallic Chemistry, 1997 - Elsevier
Publisher Summary This chapter focuses on the reactivity of (1-alkyny1) carbene complexes,
especially if a regio-and/or stereoselective formation of C, C-or C, X bonds is achieved that …