Chiral molecules containing asymmetric carbon centers bonded with nitrogen are ubiquitous
in nature and also form important structural fragments in both natural and man-made …

Organofluorine chemistry is an area of tremendous expansion. 1 The field of applications is
impressively wide in scope and has the potential to concern all fields of society. Indeed …

Cu/Ir dual catalysis has been developed for the stereodivergent α-allylation of aldimine
esters. The method enables the preparation of a series of nonproteinogenic α-amino acids …

Unnatural chiral α-tertiary amino acids containing two different carbon-based substituents at
the α-carbon centre are widespread in biologically active molecules. This sterically rigid …

The carbon–nitrogen double bonds in imines are fundamentally important functional groups
in organic chemistry. This is largely due to the fact that imines act as electrophiles towards …

Enantioenriched α‐tertiary‐α‐aminoacid and α‐chiral‐β‐aminoacid derivatives play an
important role in biological science and pharmaceutical chemistry. Thus, the development of …

New, simple, sulfinamide-based branched olefin ligands have been developed and
successfully used in Rh-catalyzed asymmetric arylations of cyclic ketimines, providing …

Because of their greater stability and unique conformational properties, unnatural amino
acids are highly valued by pharmaceutical, biological, and organic chemists. This synopsis …

Herein, we present the example of Cu-catalyzed oxidation coupling of amino acids/peptides
for producing α-alkylated unnatural glycine derivatives by the activation of double C (sp3) …

Asymmetric addition of arylboroxines to cyclic N-sulfonyl ketimines proceeded in the
presence of a rhodium catalyst coordinated with a chiral diene ligand to give high yields of …