Steric shielding effects induced by intramolecular C–H··· O Hydrogen bonding: remote borylation directed by Bpin groups

JR Montero Bastidas, A Chhabra, Y Feng… - ACS …, 2022 - ACS Publications
Regioselectivities in catalytic C–H borylations (CHBs) have been rationalized using
simplistic steric models and correlations with nuclear magnetic resonance (NMR) chemical …

Trialkoxysilane-Induced Iridium-Catalyzed para-Selective C–H Bond Borylation of Arenes

G Ju, Z Huang, Y Zhao - Nature Communications, 2024 - nature.com
An ideal approach for the construction of aryl boron compounds is to selectively replace a C–
H bond in arenes with a C–B bond, and controlling regioselectivity is one of the most …

Introduction to Spatial Anion Control for Direct C–H Arylation

J Dhankhar, I Čorić - Synlett, 2022 - thieme-connect.com
C–H activation of functionally rich molecules without the need for directing groups promises
shorter organic syntheses and late-stage diversification of molecules for drug discovery. We …