Structures of ionic liquid–water mixtures investigated by IR and NMR spectroscopy

S Cha, M Ao, W Sung, B Moon, B Ahlström… - Physical Chemistry …, 2014 - pubs.rsc.org
Imidazolium-based ionic liquids having different anions 1-butyl-3-methylimidazolium ([BMIM]
X: X= Cl−, Br−, I−, and BF4−) and their aqueous mixtures were investigated by IR absorption …

Connecting chloride solvation with hydration in deep eutectic systems

ME Di Pietro, O Hammond… - Physical Chemistry …, 2021 - pubs.rsc.org
The Deep Eutectic Solvents/Systems (DESs) choline chloride: urea (xChCl= 0.33) and
choline chloride: glycolic acid (xChCl= 0.5) were investigated using viscosity-corrected 35Cl …

Anion dynamics and motional decoupling in a glycerol–choline chloride deep eutectic solvent studied by one-and two-dimensional 35 Cl NMR

Y Hinz, J Beerwerth, R Böhmer - Physical Chemistry Chemical Physics, 2023 - pubs.rsc.org
Chlorine-35 is among the few nuclides that provide an experimental handle on the anion
dynamics in choline based deep eutectic solvents. By combining several nuclear magnetic …

[HTML][HTML] Understanding the role of temperature in structural changes of choline chloride/glycols deep eutectic solvents

F Gabriele, M Chiarini, R Germani, N Spreti - Journal of Molecular Liquids, 2023 - Elsevier
Deep eutectic solvents (DESs) represent a new “green” alternative to classic organic
solvents; however, their high viscosity often limits their utilization. The physicochemical …

[HTML][HTML] Choline chloride-water mixtures as new generation of green solvents: A comprehensive physico-chemical study

E Mangiacapre, F Castiglione, M D'Aristotile… - Journal of Molecular …, 2023 - Elsevier
Natural deep eutectic solvents (NADES) are an increasingly appreciated class of mixtures
composed by eco-sustainable and environmentally responsible components with hydrogen …

Direct Investigation of Covalently Bound Chlorine in Organic Compounds by Solid‐State 35Cl NMR Spectroscopy and Exact Spectral Line‐Shape Simulations

FA Perras, DL Bryce - Angewandte Chemie International …, 2012 - Wiley Online Library
35/37Cl NMR spectroscopy studies of organic systems are very rare, with only a few neat
liquids having been studied.[1] The lack of chlorine NMR spectroscopy data may be …

Recent advances in chlorine, bromine, and iodine solid-state NMR spectroscopy

PMJ Szell, DL Bryce - Annual Reports on NMR Spectroscopy, 2015 - Elsevier
We survey the latest advances in quadrupolar halogen (35/37 Cl, 79/81 Br, and 127 I) solid-
state nuclear magnetic resonance (SSNMR). The reporting period is from August 2008 …

Unravelling the structure of Magnus' pink salt

BEG Lucier, KE Johnston, W Xu… - Journal of the …, 2014 - ACS Publications
A combination of multinuclear ultra-wideline solid-state NMR, powder X-ray diffraction
(pXRD), X-ray absorption fine structure experiments, and first principles calculations of …

Direct investigation of halogen bonds by solid-state multinuclear magnetic resonance spectroscopy and molecular orbital analysis

J Viger-Gravel, S Leclerc, I Korobkov… - Journal of the American …, 2014 - ACS Publications
Noncovalent interactions play a ubiquitous role in the structure, stability, and reactivity of a
wide range of molecular and ionic cocrystals, pharmaceuticals, materials, and biomolecules …

Anions as dynamic probes for ionic liquid mixtures

ME Di Pietro, F Castiglione, A Mele - The Journal of Physical …, 2020 - ACS Publications
Ionic liquid (IL) mixtures have been proposed as a viable alternative to rationally fine-tune
the physicochemical properties of ILs for a variety of applications. The understanding of the …