Cu-mediated Ullmann-type cross-coupling has experienced significant advances over the
last century since the seminal publication by Ullmann in 1901. These advances have …

Primary amines are derivatives of ammonia in which one hydrogen atom is replaced by an
alkyl or aryl group. Ammonia serves as the primary nitrogen source in amination reactions …

This review summarizes recent applications of copper or copper-based compounds as a
nonprecious metal catalyst in N-nucleophiles-based dehalogenation (DH) reactions of …

Cobalt complexes with multiproton-and multielectron-responsive ligands are of interest for
challenging catalytic transformations. The chemical and redox noninnocence of pentane-2 …

Semihydrogenation of internal alkynes catalyzed by the air-stable imidazolyl amino
[Mo3S4Cl3 (ImNH2) 3]+ cluster selectively affords the (Z)-alkene under soft conditions in …

This review provides a summary of recently published developments in the field of
nonprecious metal catalysis (NPMC) and highlights the range of synthetic applications …

A general copper‐catalyzed carbonylative cross‐coupling between amines and alkyl
iodides is reported. Using a simple combination of catalytic amounts of copper (I) chloride …

Over the last fifty years, the use of nickel catalysts for facilitating organic transformations has
skyrocketed. Nickel (0) sources act as useful precatalysts because they can enter a catalytic …

Reactions where hydrogen atoms are transferred to an unsaturated substrate (X= Y) to yield
HX-YH and their microscopic reverse have a very wide scope, depending of the H atom …

Nonprecious-metal-catalyzed alternatives to powerful precious metal transformations are of
increasing interest in academia and the pharmaceutical industry due to the lower cost, better …