Organoboron compounds have become one of the most versatile building blocks in organic
synthesis owing to their accessible and efficient conversion into many different functional …

Recently, gem-diborylalkanes have attracted much attention as versatile building blocks and
fundamental intermediates in organic synthesis, because they enable multiple C–C bond …

Cyclopropane skeletons play a prominent role in the development of organic synthesis and
pharmaceutical chemistry. Herein, we report the design and synthesis of a stable …

The condensation of easy manageable lithium α-bis (boryl) carbanions with carbonyl
derivatives, the so-called boron-Wittig reaction, allows for the straightforward and often …

Recent years have witnessed an increase in the popularity of α-boryl organometallic
reagents as versatile nucleophiles in asymmetric synthesis. These compounds have been …

We describe a photo‐induced reaction for the in situ generation of highly reactive alkyl diazo
species from carbonyl precursors via photo‐excitation of N‐tosylhydrazone anions. The …

Reported herein is the efficient synthesis of tetra‐and tri‐substituted (Z)‐fluoro‐and (Z)‐
chloro‐borylalkenes by the Boron–Wittig reaction of ketones and aldehydes with bench‐top …

Geminal bis (boron) compounds have recently emerged as valuable building blocks for the
synthesis of molecules with structural diversity. They have advantages of unique stability …

We report the successful generation of (diborylmethyl) zinc (II) species by transmetallation
beteween isolable (diborylmethyl) lithium and zinc (II) halide (X= Br, Cl) and their application …

The development of boron reagents is crucial for synthetic chemistry. Herein, we present a
scalable and practical synthesis of diborodichloromethane (DBDCM) through the reaction of …