Recent advances in copper complexes for electrical/light energy conversion

Y Liu, SC Yiu, CL Ho, WY Wong - Coordination Chemistry Reviews, 2018 - Elsevier
A great deal of research effort has been put in green energy applications in the past few
decades based on organic optoelectronics. Compared with conventional inorganic …

Two-coordinate thermally activated delayed fluorescence coinage metal complexes: Molecular design, photophysical characters, and device application

TY Li, SJ Zheng, PI Djurovich, ME Thompson - Chemical Reviews, 2024 - ACS Publications
Since the emergence of the first green light emission from a fluorescent thin-film organic light
emitting diode (OLED) in the mid-1980s, a global consumer market for OLED displays has …

Radical‐type reactivity and catalysis by single‐electron transfer to or from redox‐active ligands

JI van der Vlugt - Chemistry–A European Journal, 2019 - Wiley Online Library
Controlled ligand‐based redox‐activity and chemical non‐innocence are rapidly gaining
importance for selective (catalytic) processes. This Concept aims to provide an overview of …

E-Type Delayed Fluorescence of a Phosphine-Supported Cu2(μ-NAr2)2 Diamond Core: Harvesting Singlet and Triplet Excitons in OLEDs

JC Deaton, SC Switalski, DY Kondakov… - Journal of the …, 2010 - ACS Publications
A highly emissive bis (phosphine) diarylamido dinuclear copper (I) complex (quantum yield=
57%) was shown to exhibit E-type delayed fluorescence by variable temperature emission …

Cuprophilic interactions in and between molecular entities

NVS Harisomayajula, S Makovetskyi… - Chemistry–A European …, 2019 - Wiley Online Library
Despite being weak attractive forces, closed‐shell metallophilic interactions play important
roles in the Group 11 metal complexes on their diverse structural and physical features. A …

Complexes with nitrogen‐centered radical ligands: classification, spectroscopic features, reactivity, and catalytic applications

AIO Suarez, V Lyaskovskyy, JNH Reek… - Angewandte Chemie …, 2013 - Wiley Online Library
The electronic structure, spectroscopic features, and (catalytic) reactivity of complexes with
nitrogen‐centered radical ligands are described. Complexes with aminyl ([M (. NR2)]) …

Cooperative catalysis with first‐row late transition metals

JI van der Vlugt - European Journal of Inorganic Chemistry, 2012 - Wiley Online Library
Cooperative catalysis with first‐row transition metals holds much promise for future
developments regarding sustainable, selective transformations, including eg alkenes …

A mononuclear Fe (III) single molecule magnet with a 3/2↔ 5/2 spin crossover

S Mossin, BL Tran, D Adhikari, M Pink… - Journal of the …, 2012 - ACS Publications
The air stable complex [(PNP) FeCl2](1)(PNP= N [2-P (CHMe2) 2-4-methylphenyl] 2–),
prepared from one-electron oxidation of [(PNP) FeCl] with ClCPh3, displays an unexpected …

Ligand-based redox: catalytic applications and mechanistic aspects

K Singh, A Kundu, D Adhikari - ACS Catalysis, 2022 - ACS Publications
For the last few decades, coordination chemists have seen many ligands whose role
pervades far beyond being a supporting ancillary. The ambiguity in their electronic structure …

Recent advances in well-defined, late transition metal complexes that make and/or break C–N, C–O and C–S bonds

AN Desnoyer, JA Love - Chemical Society Reviews, 2017 - pubs.rsc.org
Chemical transformations that result in either the formation or cleavage of carbon–
heteroatom bonds are among the most important processes in the chemical sciences …