Arynes hold significance for the efficient fusion of (hetero) arenes with diverse substrates,
advancing the construction of complex molecular frameworks. Employing multiple …

Conspectus Polysubstituted arenes are prevalent in numerous natural products, medicines,
agrochemicals, and organic functional materials. Among methods to prepare polysubstituted …

Recent developments in aryne chemistry are reviewed with a particular focus on synthetic
methods. This includes an overview of the precursors of arynes and their activators; the …

An aryne precursor with a potential to perform domino aryne chemistry was proposed and
synthesized. The reaction of this reagent with benzothioamide derivatives could afford 2, 4 …

Direct Thioamination of Arynes via Reaction with Sulfilimines and Migratory N-Arylation |
Journal of the American Chemical Society ACS ACS Publications C&EN CAS Find my institution …

The first total synthesis of the pentacyclic phenylnaphthacenoid type II polyketide antibiotic
formicamycin H is described. A key feature of the synthesis involves the convergent …

The ortho-directed lithiation of aromatic carbamates and carbonates causes a migration of
the substituent from the pendant O group to the adjacent C atom of the aromatic scaffold …

The recent progress made on transformations involving the reactions between aryne
intermediates and organosulfur compounds has been reviewed. A wide variety of aromatic …

Herein, we developed a new methodology of using aryl sulfonium salts as the aryne
precursor for [3+ 2] cycloaddition reactions with azides. The reaction using readily available …

To illustrate the synthetic significance of C–C activation methods, here we describe an
efficient strategy for the enantioselective total syntheses of (−)-cycloclavine and (−)-5-epi …