Although the combination of electrochemistry and homogeneous catalysis has proven to be
a powerful strategy for achieving a diverse array of novel transformations, some challenges …

Photocatalyzed and photosensitized chemical processes have seen growing interest
recently and have become among the most active areas of chemical research, notably due …

Redox processes are at the heart of synthetic methods that rely on either electrochemistry or
photoredox catalysis, but how do electrochemistry and photoredox catalysis compare? Both …

High value utilization of carbon dioxide (CO2) has attracted worldwide attention for decades.
Catalytic carboxylation of alkenes with CO2 to synthesize valuable carboxylic acids and …

For more than 70 years, nitrogen-centered radicals have been recognized as potent
synthetic intermediates. This review is a survey designed for use by chemists engaged in …

Photoredox chemistry with organic or transition metal agents has been reviewed in earlier
years, but such is the pace of progress that we will overlap very little with earlier …

The fields of C–H functionalization and photoredox catalysis have garnered enormous
interest and utility in the past several decades. Many different scientific disciplines have …

Skeletal ring enlargement is gaining renewed interest in synthetic chemistry and has
recently focused on insertion of one or two atoms. Strategies for heterocyclic expansion …

Coordination complexes of precious metals with the d6 valence electron configuration such
as Ru (II), Os (II) and Ir (III) are used for lighting applications, solar energy conversion and …

As the breadth of radical chemistry grows, new means to promote and regulate single-
electron redox activities play increasingly important roles in driving modern synthetic …