Chemistry of s-, p-and f-block metal complexes with ene-diamido ligands
Y Bai, W Chen, J Li, C Cui - Coordination Chemistry Reviews, 2019 - Elsevier
The α-ene-diamido ligands (the reduced form of α-diimine) have been extensively studied
as supporting ligands for s-, p-and f-block elements over the last several decades. They not …
as supporting ligands for s-, p-and f-block elements over the last several decades. They not …
Redox-active α-diimine complexes of early transition metals: From bonding to catalysis
K Mashima - Bulletin of the Chemical Society of Japan, 2020 - academic.oup.com
It is an intrinsic nature that early transition metals favorably adopt their highest oxidation
state with d0 configuration. We have been interested in early transition metal complexes …
state with d0 configuration. We have been interested in early transition metal complexes …
End-Functionalized Polymerization of 2-Vinylpyridine through Initial C–H Bond Activation of N-Heteroaromatics and Internal Alkynes by Yttrium Ene–Diamido …
H Kaneko, H Nagae, H Tsurugi… - Journal of the American …, 2011 - ACS Publications
We successfully introduced end-capping functional groups to poly (2-vinylpyridine) s by
initial introduction of the functional groups on yttrium catalysts through C–H bond activation …
initial introduction of the functional groups on yttrium catalysts through C–H bond activation …
Catalytic Selective Dihydrosilylation of Internal Alkynes Enabled by Rare‐Earth Ate Complex
W Chen, H Song, J Li, C Cui - … Chemie International Edition, 2020 - Wiley Online Library
Hydrosilylation of alkynes generally yield vinylsilanes, which are inert to the further
hydrosilylation because of the steric effects. Reported here is the first successful …
hydrosilylation because of the steric effects. Reported here is the first successful …
Ytterbium and europium complexes of redox-active ligands: searching for redox isomerism
IL Fedushkin, DS Yambulatov, AA Skatova… - Inorganic …, 2017 - ACS Publications
The reaction of (dpp-Bian) EuII (dme) 2 (3)(dpp-Bian is dianion of 1, 2-bis [(2, 6-
diisopropylphenyl) imino] acenaphthene; dme is 1, 2-dimethoxyethane) with 2, 2 …
diisopropylphenyl) imino] acenaphthene; dme is 1, 2-dimethoxyethane) with 2, 2 …
Carbon Radical Generation by d0 Tantalum Complexes with α-Diimine Ligands through Ligand-Centered Redox Processes
High-valent tantalum complexes having redox-active α-diimine ligands,(α-diimine) TaCl n
(n= 3, 4), are prepared by the reaction of TaCl5, α-diimine ligands, and an organosilicon …
(n= 3, 4), are prepared by the reaction of TaCl5, α-diimine ligands, and an organosilicon …
Structural and electronic noninnocence of α-Diimine ligands on niobium for reductive C–Cl bond activation and catalytic radical addition reactions
H Nishiyama, H Ikeda, T Saito, B Kriegel… - Journal of the …, 2017 - ACS Publications
A d0 niobium (V) complex, NbCl3 (α-diimine)(1a), supported by a dianionic redox-active N,
N′-bis (2, 6-diisopropylphenyl)-1, 4-diaza-2, 3-dimethyl-1, 3-butadiene (α-diimine) ligand …
N′-bis (2, 6-diisopropylphenyl)-1, 4-diaza-2, 3-dimethyl-1, 3-butadiene (α-diimine) ligand …
Rare-earth-catalyzed regioselective hydrosilylation of aryl-substituted internal alkenes
J Liu, W Chen, J Li, C Cui - ACS Catalysis, 2018 - ACS Publications
Rare-earth-catalyzed regioselective hydrosilylation of internal alkenes with an ene-diamido
samarium alkyl as a precatalyst has been described. The samarium alkyl complex …
samarium alkyl as a precatalyst has been described. The samarium alkyl complex …
Lanthanum complexes with a diimine ligand in three different redox states
IL Fedushkin, AN Lukoyanov, EV Baranov - Inorganic Chemistry, 2018 - ACS Publications
The reduction of 1, 2-bis [(2, 6-diisopropylphenyl) imino] acenaphthene (dpp-Bian) with an
excess of La metal in the presence of iodine (dpp-Bian/I2= 2/1) in tetrahydrofuran (thf) or …
excess of La metal in the presence of iodine (dpp-Bian/I2= 2/1) in tetrahydrofuran (thf) or …
Rare-earth dichloro and bis (alkyl) complexes supported by bulky amido–imino ligand. Synthesis, structure, reactivity and catalytic activity in isoprene polymerization
AA Kissel, DM Lyubov, TV Mahrova, GK Fukin… - Dalton …, 2013 - pubs.rsc.org
A monoanionic amido–imino ligand system [(2, 6-iPr2C6H3) NC (Me) C (CH2) N (C6H3-2, 6-
iPr2)]− was successfully employed for the synthesis of monomeric dichloro [(2, 6-iPr2C6H3) …
iPr2)]− was successfully employed for the synthesis of monomeric dichloro [(2, 6-iPr2C6H3) …