Molecular catalysis plays an essential role in both natural and artificial photosynthesis (AP).
However, the field of molecular catalysis for AP has gradually declined in recent years …

Hydrogen emerges as one of the cleanest and most renewable energy resources for fossil
fuel alternatives. Commercial-scale hydrogen production through water-splitting …

Efficient hydrogen generation from aqueous protons through direct conversion of solar
energy is an essential prerequisite of a future hydrogen economy and easily accessible …

Biological systems provide attractive reactivity blueprints for the design of challenging
chemical transformations. Emulating the operating mode of natural systems may however …

Electrocatalytic hydrogen evolution reaction (HER) is a critical process in a sustainable
energy conversion system. Many metal complexes as small-molecule catalysts for …

In this study, we report the electrocatalytic behavior of the neutral, monomeric Ni (II) complex
of diacetyl-bis (N-4-methyl-3-thiosemicarbazonato), NiL1, for ligand-assisted metal-centered …

In the past decade, the use of redox-active ligands has emerged as a promising strategy to
improve catalyst selectivity, efficiency, and stability in electroassisted H+ and CO2 …

Quantum chemical approaches today are a powerful tool to study the properties and
reactivity of metalloenzymes. In the field of solar fuels research these involve predominantly …

In this study, we report a pair of electrocatalysts for the hydrogen evolution reaction (HER)
based on the noninnocent ligand diacetyl-2-(4-methyl-3-thiosemicarbazone)-3-(2 …

Iron-sulphur cofactors in the reactive sites of metalloproteins such as Fe-Fe-hydrogenase
have played key roles in biological redox reactions such as the generation and activation of …