Increasing iridium oxide activity for the oxygen evolution reaction with hafnium modification

F Zhao, B Wen, W Niu, Z Chen, C Yan… - Journal of the …, 2021 - ACS Publications
Synthesis and implementation of highly active, stable, and affordable electrocatalysts for the
oxygen evolution reaction (OER) is a major challenge in developing energy efficient and …

Nickel–iron oxyhydroxide oxygen-evolution electrocatalysts: the role of intentional and incidental iron incorporation

L Trotochaud, SL Young, JK Ranney… - Journal of the …, 2014 - ACS Publications
Fe plays a critical, but not yet understood, role in enhancing the activity of the Ni-based
oxygen evolution reaction (OER) electrocatalysts. We report electrochemical, in situ …

Water oxidation on a mononuclear manganese heterogeneous catalyst

J Guan, Z Duan, F Zhang, SD Kelly, R Si, M Dupuis… - Nature Catalysis, 2018 - nature.com
Water oxidation is the prerequisite for dioxygen evolution in natural or artificial
photosynthesis. Although it has been demonstrated that multinuclear active sites are …

Single Atom Hot-Spots at Au–Pd Nanoalloys for Electrocatalytic H2O2 Production

JS Jirkovský, I Panas, E Ahlberg… - Journal of the …, 2011 - ACS Publications
A novel strategy to direct the oxygen reduction reaction to preferentially produce H2O2 is
formulated and evaluated. The approach combines the inertness of Au nanoparticles toward …

Beyond the top of the volcano?–A unified approach to electrocatalytic oxygen reduction and oxygen evolution

M Busch, NB Halck, UI Kramm, S Siahrostami, P Krtil… - Nano Energy, 2016 - Elsevier
We study the oxygen reduction (ORR) and the oxygen evolution reaction (OER) and based
on previous obtained mechanistic insight we provide a unified general analysis of the two …

Water oxidation: From mechanisms to limitations

M Busch - Current Opinion in Electrochemistry, 2018 - Elsevier
Water oxidation is a central reaction for energy conversion and storage. On the basis of the
detailed analysis of different reaction mechanisms the limitations associated with the O 2 …

Tin doping speeds up hole transfer during light-driven water oxidation at hematite photoanodes

HK Dunn, JM Feckl, A Müller… - Physical Chemistry …, 2014 - pubs.rsc.org
Numerous studies have shown that the performance of hematite photoanodes for light-
driven water splitting is improved substantially by doping with various metals, including tin …

The oxygen evolution reaction: mechanistic concepts and catalyst design

RL Doyle, MEG Lyons - … Solar Fuel Production: From Basic Principles to …, 2016 - Springer
Fundamental aspects of the oxygen evolution reaction mediated by metal oxide catalysts are
presented. The oxygen evolution reaction is a critical bottleneck in the generation of …

Revisiting the redox properties of hydrous iridium oxide films in the context of oxygen evolution

P Steegstra, M Busch, I Panas… - The Journal of Physical …, 2013 - ACS Publications
The electrochemistry of hydrous iridium oxide films (HIROF) is revisited. Cyclic
voltammograms of HIROFs display two reversible redox couples commonly assigned to the …

Spin catalysts: A quantum trigger for chemical reactions

OV Khavryuchenko, VD Khavryuchenko… - Chinese Journal of …, 2015 - Elsevier
Spin catalysis allows restrictions of the spin conservation rule to be overcome, and,
moreover, provides a tool for fine control of elementary reactions. Spin-conductive solid …