Corroles at work: A small macrocycle for great applications

C Di Natale, CP Gros, R Paolesse - Chemical Society Reviews, 2022 - pubs.rsc.org
Corrole chemistry has witnessed an impressive boost in studies in the last 20 years, thanks
to the possibility of preparing corrole derivatives by simple synthetic procedures. The …

Theory and calculation of the phosphorescence phenomenon

G Baryshnikov, B Minaev, H Ågren - Chemical reviews, 2017 - ACS Publications
Phosphorescence is a phenomenon of delayed luminescence that corresponds to the
radiative decay of the molecular triplet state. As a general property of molecules …

Electronic structure of corrole derivatives: insights from molecular structures, spectroscopy, electrochemistry, and quantum chemical calculations

A Ghosh - Chemical Reviews, 2017 - ACS Publications
Presented herein is a comprehensive account of the electronic structure of corrole
derivatives. Our knowledge in this area derives from a broad range of methods, including UV …

Strategies for corrole functionalization

JFB Barata, MGPMS Neves, MAF Faustino… - Chemical …, 2017 - ACS Publications
This review covers the functionalization reactions of meso-arylcorroles, both at the inner
core, as well as the peripheral positions of the macrocycle. Experimental details for the …

Luminescent chemosensors by using cyclometalated iridium (III) complexes and their applications

DL Ma, S Lin, W Wang, C Yang, CH Leung - Chemical science, 2017 - pubs.rsc.org
Luminescent metal complexes have found increasing use in multiple areas of science and
technology, including in chemosensing, light-emitting devices and photochemistry. In …

Corrole photochemistry

CM Lemon - Pure and Applied Chemistry, 2020 - degruyter.com
The rapid expansion of photoredox catalysis and artificial photosynthesis has garnered
renewed interest in the field of photochemistry. While porphyrins have been widely utilized …

Luminescent ruffled iridium (iii) porphyrin complexes containing N-heterocyclic carbene ligands: structures, spectroscopies and potent antitumor activities under dark …

TL Lam, KC Tong, C Yang, WL Kwong, X Guan… - Chemical …, 2019 - pubs.rsc.org
A panel of iridium (III) porphyrin complexes containing axial N-heterocyclic carbene (NHC)
ligand (s) were synthesized and characterized. X-ray crystal structures of the bis-NHC …

Osmium-nitrido corroles as NIR indicators for oxygen sensors and triplet sensitizers for organic upconversion and singlet oxygen generation

SM Borisov, A Alemayehu, A Ghosh - Journal of Materials Chemistry C, 2016 - pubs.rsc.org
The photophysical properties of nitridoosmium (VI) corroles have been investigated. The
complexes exhibit room temperature NIR phosphorescence (λmax 779–795 nm). Long …

Near-infrared emitting iridium (III) complexes for mitochondrial imaging in living cells

Y Liu, P Zhang, X Fang, G Wu, S Chen, Z Zhang… - Dalton …, 2017 - pubs.rsc.org
Biocompatible transition metal complexes dyes emitting in the near-infrared (NIR) region,
are highly desirable in fluorescence imaging techniques. However, a high-performance …

Synthesis, characterization, and reactivities of high valent metal–corrole (M= Cr, Mn, and Fe) complexes

S Mondal, PK Naik, JK Adha, S Kar - Coordination Chemistry Reviews, 2019 - Elsevier
For the first-row middle transition metals (Cr, Mn, and Fe), the formal oxidation states are
relatively lower. However, biological systems in various enzymatic reactions rely extensively …