An iridium‐catalyzed remote site‐switchable hydroarylation of alkenes was reported,
delivering the products functionalized at the subterminal methylene and terminal methyl …

Catalytic formation of a regio-and enantioselective C–F bond chiral center from readily
available alkenes is a crucial goal, yet it continues to pose significant challenges in organic …

Transition metal-catalyzed enantioselective hydroamination of 1, 3-dienes provides a direct
methodology for the construction of chiral allylamines. So far, all of the reported examples …

Abstract β‐Branched chiral amines with contiguous stereocenters are valuable building
blocks for preparing various biologically active molecules. However, their asymmetric …

Silanes, a simple and common hydride source, are emphasized for their chemical stability,
neat and easy-to-handle and usually not requiring any precautions upon activation by nickel …

A Ni-catalyzed enantioselective hydroamination of vinylarenes has been developed,
affording a wide variety of α-branched chiral alkylamines in good yields with exclusive …

Here we present a highly efficient protocol utilizing nickel-hydride hydrogen atom transfer
catalysis for the regio-and enantioselective hydrofluorination of internal alkenes. This …

The conventional approach to developing asymmetric synthetic methods relies heavily on
empirical optimization. However, the integration of artificial intelligence (AI) and high …

The stereoselective synthesis of β-amino acids has attracted major attention among the
synthetic community in recent years. This review provides an overview of the important …

Enantioselective recognition is a fundamental property of chiral linkers in chiral metal–
organic frameworks (CMOFs). However, clarifying the efficient enantioselective …