Photochemical approaches to complex chemotypes: applications in natural product synthesis

MD Karkas, JA Porco Jr, CRJ Stephenson - Chemical Reviews, 2016 - ACS Publications
The use of photochemical transformations is a powerful strategy that allows for the formation
of a high degree of molecular complexity from relatively simple building blocks in a single …

Structure, synthesis, biosynthesis, and activity of the characteristic compounds from Ginkgo biloba L.

XG Liu, X Lu, W Gao, P Li, H Yang - Natural Product Reports, 2022 - pubs.rsc.org
Covering: 1928–2021 Ginkgo biloba L. is one of the most distinctive plants to have emerged
on earth and has no close living relatives. Owing to its phylogenetic divergence from other …

Catalyst-controlled site-selective methylene C–H lactonization of dicarboxylic acids

HSS Chan, JM Yang, JQ Yu - Science, 2022 - science.org
Catalyst-controlled site-selective activation of β-and γ-methylene carbon-hydrogen (C–H)
bonds of free carboxylic acids is a long-standing challenge. Here we show that, with a pair of …

Palladium‐catalyzed cross‐coupling reactions in total synthesis

KC Nicolaou, PG Bulger… - Angewandte Chemie …, 2005 - Wiley Online Library
In studying the evolution of organic chemistry and grasping its essence, one comes quickly
to the conclusion that no other type of reaction plays as large a role in shaping this domain …

Synthetic strategies toward natural products containing contiguous stereogenic quaternary carbon atoms

M Bueschleb, S Dorich, S Hanessian… - Angewandte Chemie …, 2016 - Wiley Online Library
Strategies for the total synthesis of complex natural products that contain two or more
contiguous stereogenic quaternary carbon atoms in their intricate structures are reviewed …

Palladiumkatalysierte kreuzkupplungen in der totalsynthese

KC Nicolaou, PG Bulger, D Sarlah - Angewandte Chemie, 2005 - Wiley Online Library
Wenn man die Entwicklung der organischen Chemie betrachtet, kommt man schnell zu dem
Schluss, dass kein Reaktionstyp dieses Gebiet in vergleichbarer Weise geprägt hat wie die …

Radical chemistry associated with the thiocarbonyl group

D Crich, L Quintero - Chemical Reviews, 1989 - ACS Publications
The inherent weakness of the thiocarbonyl bond with its low coefficient of C2p'r-S3pT orbital
overlap leads to a rich and varied chemistry, photochemical1 and nonradical2 aspects of …

The B aeyer–V illiger Oxidation of Ketones and Aldehydes

GR Krow - Organic reactions, 2004 - Wiley Online Library
The oxidative conversion of alicyclic ketones into lactones with permonosulfuric acid was
discovered by Baeyer and Villiger in 1899, and in their honor the general process by which …

Organocopper reagents: substitution, conjugate addition, carbo/metallocupration, and other reactions

BH Lipshutz, S Sengupta - Organic Reactions, 2004 - Wiley Online Library
Well over a decade ago, two reviews were contributed to the Organic Reactions series
covering substitution and conjugate addition reactions in organocopper chemistry. Their …

Applications of oxaziridines in organic synthesis

FA Davis, AC Sheppard - Tetrahedron, 1989 - Elsevier
Oxaziridines 1, heterocyclic compounds containing oxygen, nitrogen and carbon atoms in a
threemembered ring, were first reported in the mid-fifties by Krimm,* Emmons' and Homer …