Creation from Confusion and Fusion in the Porphyrin World─ The Last Three Decades of N-Confused Porphyrinoid Chemistry

M Toganoh, H Furuta - Chemical Reviews, 2022 - ACS Publications
Confusion is a novel concept of isomerism in porphyrin chemistry, delivering a steady
stream of new chemistry since the discovery of N-confused porphyrin, a porphyrin mutant, in …

Metal catalyst for CO2 capture and conversion into cyclic carbonate: Progress and challenges

P Tyagi, D Singh, N Malik, S Kumar, RS Malik - Materials Today, 2023 - Elsevier
Fossil fuel has empowered a remarkable era of prosperity and development of the welfare of
human society. However, the resulting large anthropogenic CO 2 emissions had an adverse …

Metal complexes of porphyrinoids containing nonpyrrolic heterocycles

DW Thuita, C Brückner - Chemical Reviews, 2022 - ACS Publications
The replacement of one or more pyrrolic building block (s) of a porphyrin by a nonpyrrolic
heterocycle leads to the formation of so-called pyrrole-modified porphyrins (PMPs) …

Organometallic chemistry confined within a porphyrin-like framework

MJ Białek, K Hurej, H Furuta… - Chemical Society …, 2023 - pubs.rsc.org
The world of modified porphyrins changed forever when an N-confused porphyrin (NCP), a
porphyrin isomer, was first published in 1994. The replacement of one inner nitrogen with a …

Chemical fixation of CO 2 into cyclic carbonates catalyzed by bimetal mixed MOFs: the role of the interaction between Co and Zn

Y Wu, X Song, S Xu, Y Chen, O Oderinde, L Gao… - Dalton …, 2020 - pubs.rsc.org
Bimetal mixed MOFs of [CoZn][(BDC)(DABCO) 0.5](CZ-BDO),[CoNi][(BDC)(DABCO) 0.5](CN-
BDO), and [NiZn][(BDC)(DABCO) 0.5](NZ-BDO) were prepared under solvothermal …

Sn (iv) N-confused porphyrins as photosensitizer dyes for photodynamic therapy in the near IR region

B Babu, J Mack, T Nyokong - Dalton Transactions, 2020 - pubs.rsc.org
The utility of Sn (IV) N-confused porphyrin (SnNCP) for use as photosensitizer dyes in
photodynamic therapy is investigated. SnNCP has an unusually high singlet oxygen …

Chemical fixation of carbon dioxide catalyzed via hydroxyl and carboxyl-rich glucose carbonaceous material as a heterogeneous catalyst

RB Mujmule, WJ Chung, H Kim - Chemical Engineering Journal, 2020 - Elsevier
Chemical fixation of carbon dioxide (CO 2) is among the fundamental pathways to
considerably decrease its accumulation in the atmosphere. Herein, we present utilization of …

Molecular engineered palladium single atom catalysts with an MC 1 N 3 subunit for Suzuki coupling

J Liu, Z Chen, C Liu, B Zhang, Y Du, CF Liu… - Journal of Materials …, 2021 - pubs.rsc.org
Single atom catalysis has emerged as a powerful technique for catalysis due to its
outstanding performance and atom economy. Controlling the hybridization of the atom with …

Mn (iii)–porphyrin catalysts for the cycloaddition of CO 2 with epoxides at atmospheric pressure: effects of Lewis acidity and ligand structure

BN Cabral, JLS Milani, AM Meireles… - New Journal of …, 2021 - pubs.rsc.org
A series of eight Mn (III)–porphyrin (MnP) complexes with electron-withdrawing substituents
at the meso and/or β-pyrrole positions of the macrocycle was designed to uncover electronic …

Nickel–cobalt hydroxide catalysts for the cycloaddition of carbon dioxide to epoxides

SLS Ribeiro, CG Silva, GETO Prado… - Research on Chemical …, 2022 - Springer
Nickel and cobalt bimetallic hydroxides, in which both metal cations present the same
oxidation state, were synthesized and characterized by XRD, TGA, TEM, XPS, and ICP-OES …