Taking the plunge: chemical reaction dynamics in liquids

AJ Orr-Ewing - Chemical Society Reviews, 2017 - pubs.rsc.org
The dynamics of chemical reactions in liquid solutions are now amenable to direct study
using ultrafast laser spectroscopy techniques and advances in computer simulation …

Switching between coherent and incoherent singlet fission via solvent-induced symmetry breaking

AM Alvertis, S Lukman, TJH Hele… - Journal of the …, 2019 - ACS Publications
Singlet fission in organic semiconductors causes a singlet exciton to decay into a pair of
triplet excitons and holds potential for increasing the efficiency of photovoltaic devices. In …

Intramolecular vibrational energy redistribution and the quantum ergodicity transition: a phase space perspective

S Karmakar, S Keshavamurthy - Physical Chemistry Chemical Physics, 2020 - pubs.rsc.org
Intramolecular vibrational energy redistribution (IVR) impacts the dynamics of reactions in a
profound way. Theoretical and experimental studies are increasingly indicating that …

The full dynamics of energy relaxation in large organic molecules: from photo-excitation to solvent heating

V Balevičius Jr, T Wei, D Di Tommaso… - Chemical …, 2019 - pubs.rsc.org
In some molecular systems, such as nucleobases, polyenes or the active ingredients of
sunscreens, substantial amounts of photo-excitation energy are dissipated on a sub …

Infrared laser excitation controlled reaction acceleration in the electronic ground state

K Heyne, O Kühn - Journal of the American Chemical Society, 2019 - ACS Publications
Propelling a ground state reaction by mode-specific vibrational excitation via infrared (IR)
light offers a novel route to carry out ground state chemistry. Here, we describe the …

Full relaxation dynamics recovery from ultrafast fluorescence experiments by means of the stochastic model: Does the solvent response dynamics depend on the …

AE Nazarov, AI Ivanov, A Rosspeintner… - Journal of Molecular …, 2022 - Elsevier
An approach to analysing time-resolved fluorescence spectra has been developed for dyes
with non-parabolic free energy curves of the excited and ground states. It incorporates the …

Unraveling the Ultrafast Photochemical Dynamics of Nitrobenzene in Aqueous Solution

NA Lau, D Ghosh, S Bourne-Worster… - Journal of the …, 2024 - ACS Publications
Nitroaromatic compounds are major constituents of the brown carbon aerosol particles in the
troposphere that absorb near-ultraviolet (UV) and visible solar radiation and have a …

Separation of an Industrial Mixture of Decalin or Naphthalene Fluorination Products: Cis-Perfluorodecalin, Trans-Perfluorodecalin and Perfluoro (butylcyclohexane) …

EV Lupachev, AA Voshkin, AV Kisel', NN Kulov… - Processes, 2023 - mdpi.com
New physicochemical data for trans-perfluorodecalin (trans-PDF) and cis-perfluorodecalin
(cis-PFD) are presented. Based on the differential scanning calorimetry, the temperature and …

3D bending simulation and mechanical properties of the OLED bending area

L Ma, J Gu - Open Physics, 2020 - degruyter.com
Due to the poor mechanical properties of traditional simulation models of the organic light-
emitting device (OLED) bending area, this article puts forward a finite element model of 3D …

Photophysics of Benzoxazole and Dicyano Functionalised Diketopyrrolopyrrole Derivatives: Insights into Ultrafast Processes and the Triplet State

YR Panthi, MA Thottappali, P Horáková… - …, 2024 - Wiley Online Library
Diketopyrrolopyrrole (DPP) functionalised with an electron donating unit acts as a donor‐
acceptor molecules that have shown potential for application in dyes and photovoltaics …