Recent advances in organocatalytic asymmetric morita–baylis–hillman/aza-morita–baylis–hillman reactions

Y Wei, M Shi - Chemical reviews, 2013 - ACS Publications
1. INTRODUCTION The carbon− carbon bond forming reactions is one of the most important
reactions in organic chemistry, and therefore has been and remains an important and a …

Recent advances in organocatalytic methods for the synthesis of disubstituted 2-and 3-indolinones

R Dalpozzo, G Bartoli, G Bencivenni - Chemical Society Reviews, 2012 - pubs.rsc.org
In recent years, organocatalysis has enhanced its importance as a tool for the synthesis of
enantiomerically enriched compounds. Among the candidates for organocatalysis, the …

Alternative energy input: mechanochemical, microwave and ultrasound-assisted organic synthesis

RBN Baig, RS Varma - Chemical Society Reviews, 2012 - pubs.rsc.org
Microwave, ultrasound, sunlight and mechanochemical mixing can be used to augment
conventional laboratory techniques. By applying these alternative means of activation, a …

Recent contributions from the Baylis− Hillman reaction to organic chemistry

D Basavaiah, BS Reddy, SS Badsara - Chemical reviews, 2010 - ACS Publications
Organic synthesis is one of the most successful and useful disciplines of science and mainly
involves the construction of carbon-carbon bond (s) and carbon-heteroatom bond (s) and …

Lewis base catalysis in organic synthesis

SE Denmark, GL Beutner - Angewandte Chemie International …, 2008 - Wiley Online Library
Abstract The legacy of Gilbert Newton Lewis (1875–1946) pervades the lexicon of chemical
bonding and reactivity. The power of his concept of donor–acceptor bonding is evident in the …

Quantum mechanical investigations of organocatalysis: mechanisms, reactivities, and selectivities

PHY Cheong, CY Legault, JM Um… - Chemical …, 2011 - ACS Publications
Organocatalysis has captured the imagination of a significant group of synthetic chemists.
Much of the mechanistic understanding of these reactions has come from computational …

Organocatalysis mediated by (thio) urea derivatives

SJ Connon - Chemistry–A European Journal, 2006 - Wiley Online Library
Over the last decade the potential for N, N‐dialkyl (thio) urea derivatives to serve as active
metal‐free organocatalysts for a wide range of synthetically useful reactions susceptible to …

Multifunctional chiral phosphine organocatalysts in catalytic asymmetric Morita− Baylis− Hillman and related reactions

Y Wei, M Shi - Accounts of chemical research, 2010 - ACS Publications
Catalytic asymmetric synthesis has received considerable attention over the past few
decades, becoming a highly dynamic area of chemical research with significant …

Synthesis of chiral cyclopentenones

SP Simeonov, JPM Nunes, K Guerra… - Chemical …, 2016 - ACS Publications
The cyclopentenone unit is a very powerful synthon for the synthesis of a variety of bioactive
target molecules. This is due to the broad diversity of chemical modifications available for …

Recent advances in catalytic asymmetric synthesis of allenes

WD Chu, Y Zhang, J Wang - Catalysis Science & Technology, 2017 - pubs.rsc.org
Allene moieties with axial chirality are featured in many natural products with biological
activities. They also serve as unique building blocks in organic synthesis and as chiral …