Carbonyl–olefin metathesis

H Albright, AJ Davis, JL Gomez-Lopez… - Chemical …, 2021 - ACS Publications
This Review describes the development of strategies for carbonyl–olefin metathesis
reactions relying on stepwise, stoichiometric, or catalytic approaches. A comprehensive …

Merging carbonyl addition with photocatalysis

HM Huang, P Bellotti, F Glorius - Accounts of Chemical Research, 2022 - ACS Publications
Conspectus The carbonyl group stands as a fundamental scaffold and plays a ubiquitous
role in synthetically important chemical reactions in both academic and industrial contexts …

Palladium-catalyzed carbon-sulfur or carbon-phosphorus bond metathesis by reversible arylation

Z Lian, BN Bhawal, P Yu, B Morandi - Science, 2017 - science.org
Compounds bearing aryl-sulfur and aryl-phosphorus bonds have found numerous
applications in drug development, organic materials, polymer science, and homogeneous …

Catalytic isofunctional reactions—expanding the repertoire of shuttle and metathesis reactions

BN Bhawal, B Morandi - Angewandte Chemie International …, 2019 - Wiley Online Library
Transfer hydrogenation, alkene metathesis, and alkyne metathesis possess great value to
the synthetic chemistry community. One of the key features of these processes is their …

Beyond olefins: new metathesis directions for synthesis

MR Becker, RB Watson, CS Schindler - Chemical Society Reviews, 2018 - pubs.rsc.org
The olefin–olefin metathesis reaction has emerged as one of the most important carbon–
carbon bond-forming reactions, as illustrated by its wide use in the synthesis of complex …

Metathesis-active ligands enable a catalytic functional group metathesis between aroyl chlorides and aryl iodides

YH Lee, B Morandi - Nature Chemistry, 2018 - nature.com
Current methods for functional group interconversion have, for the most part, relied on
relatively strong driving forces which often require highly reactive reagents to generate …

Brønsted Acid‐Catalyzed Carbonyl‐Olefin Metathesis inside a Self‐Assembled Supramolecular Host

L Catti, K Tiefenbacher - Angewandte Chemie International …, 2018 - Wiley Online Library
Carbonyl–olefin metathesis represents a powerful yet underdeveloped method for the
formation of carbon–carbon bonds. So far, no Brønsted acid based method for the catalytic …

Mechanistic investigations of the iron (III)-catalyzed carbonyl-olefin metathesis reaction

JR Ludwig, S Phan, CC McAtee… - Journal of the …, 2017 - ACS Publications
Iron (III)-catalyzed carbonyl-olefin ring-closing metathesis represents a new approach
toward the assembly of molecules traditionally generated by olefin–olefin metathesis or …

Catalytic carbonyl-olefin metathesis of aliphatic ketones: Iron (III) homo-dimers as lewis acidic superelectrophiles

H Albright, PS Riehl, CC McAtee, JP Reid… - Journal of the …, 2018 - ACS Publications
Catalytic carbonyl-olefin metathesis reactions have recently been developed as a powerful
tool for carbon–carbon bond formation. However, currently available synthetic protocols rely …

Tropylium-promoted carbonyl–olefin metathesis reactions

UPN Tran, G Oss, DP Pace, J Ho, TV Nguyen - Chemical science, 2018 - pubs.rsc.org
The carbonyl–olefin metathesis (COM) reaction is a highly valuable chemical transformation
in a broad range of applications. However, its scope is much less explored compared to …