This review describes the additions of allylmagnesium reagents to carbonyl compounds and
to imines, focusing on the differences in reactivity between allylmagnesium halides and …

Numerous procedures focus on inserting the fluorine atom into the carbon frameworks of
synthetically useful target molecules using various nucleophilic fluorinating reagents …

The ability to use racemic allylic trichloroacetimidates as competent electrophiles in a chiral
bicyclo [3.3. 0] octadiene-ligated iridium-catalyzed asymmetric fluorination with Et3N· 3HF is …

The amination of racemic secondary and tertiary allylic trichloroacetimidates possessing β-
nitrogen substituents and proximal nitrogen-containing heterocycles, via chiral diene-ligated …

Abstract An efficient Pd (0)-catalyzed deacylative allylation (DaA) of enolcarbonates (pro-
nucleophile) prepared from 2-arylcyclohexanones sharing acyl functionality at C2-position …

Natural product synthesis has been the prime focus for the development of new carbon‐
carbon bond forming transformations. In particular, the construction of molecules with all …

The Mitsunobu reaction was employed in a key step during the development of a convenient
synthetic route for the enantioselective preparation of pyrrolidine-sulfamide ligands from (R) …

The ability to use racemic allylic trichloroacetimidates as competent electrophiles in a chiral
bicyclo [3.3. 0] octadiene-ligated iridium-catalyzed asymmetric fluorination with Et 3 N• 3HF …

The incorporation of fluorine atoms has far-reaching impacts in organic chemistry. Over the
past decade, molecules containing carbon-fluorine bonds have become increasingly …

Segundo dados da Organização Mundial da Saúde, cerca de 13% da população mundial é
classificada como obesa (2016). Consequentemente, há um elevado gasto em saúde para …