Organoelement chemistry: Promising growth areas and challenges

GA Abakumov, AV Piskunov… - Russian Chemical …, 2018 - iopscience.iop.org
The chemistry of organoelement compounds is now one of the most rapidly developing
fields of research, regarding both fundamental science and solution of applied problems …

[HTML][HTML] Acetylene in organic synthesis: Recent progress and new uses

VV Voronin, MS Ledovskaya, AS Bogachenkov… - Molecules, 2018 - mdpi.com
Recent progress in the leading synthetic applications of acetylene is discussed from the
prospect of rapid development and novel opportunities. A diversity of reactions involving the …

Calcium‐based sustainable chemical technologies for total carbon recycling

KS Rodygin, YA Vikenteva, VP Ananikov - ChemSusChem, 2019 - Wiley Online Library
Calcium carbide, a stable solid compound composed of two atoms of carbon and one of
calcium, has proven its effectiveness in chemical synthesis, due to the safety and …

Calcium carbide: A unique reagent for organic synthesis and nanotechnology

KS Rodygin, G Werner, FA Kucherov… - Chemistry–An Asian …, 2016 - Wiley Online Library
Abstract Acetylene, HC≡ CH, is one of the primary building blocks in synthetic organic and
industrial chemistry. Several highly valuable processes have been developed based on this …

Catalyst‐Dependent Stereospecific [3,3]‐Sigmatropic Rearrangement of Sulfoxide‐Ynamides: Divergent Synthesis of Chiral Medium‐Sized N,S‐Heterocycles

GY Zhu, JJ Zhou, LG Liu, X Li, XQ Zhu, X Lu… - Angewandte …, 2022 - Wiley Online Library
Medium‐sized N, S‐heterocycles have received tremendous interest due to their biological
activities and potential medical applications. However, asymmetric synthesis of these …

Organic and hybrid systems: from science to practice

VP Ananikov, DB Eremin, SA Yakukhnov… - Mendeleev …, 2017 - Elsevier
Organic systems still dominate several traditional areas of chemical science and well-known
applications, such as the synthesis of pharmaceutical compounds and drugs. However, a …

Copper-Catalyzed Construction of Benzo[4,5]imidazo[2,1-a]isoquinolines Using Calcium Carbide as a Solid Alkyne Source

H Liu, Z Li - Organic Letters, 2021 - ACS Publications
A method for the synthesis of benzo [4, 5] imidazo [2, 1-a] isoquinolines through
Sonogashira cross-coupling/nucleophilic addition tandem reactions using calcium carbide …

Calcium carbide: Versatile synthetic applications, green methodology and sustainability

KS Rodygin, MS Ledovskaya… - European Journal of …, 2021 - Wiley Online Library
Acetylene is a key building block for organic chemistry and potentially can be involved in a
diverse range of synthetic transformations. However, critical analysis of practical …

[3 + 2]-Cycloaddition of in Situ Generated Nitrile Imines and Acetylene for Assembling of 1,3-Disubstituted Pyrazoles with Quantitative Deuterium Labeling

VV Voronin, MS Ledovskaya, EG Gordeev… - The Journal of …, 2018 - ACS Publications
A novel synthetic methodology for the preparation of 1, 3-disubstituted pyrazoles from in situ
generated nitrile imines and acetylene is reported. The reactions are performed in a simple …

Altering Copper‐Catalyzed A3 Couplings by Mechanochemistry: One‐Pot Synthesis of 1,4‐Diamino‐2‐butynes from Aldehydes, Amines, and Calcium Carbide

M Turberg, KJ Ardila‐Fierro, C Bolm… - Angewandte Chemie …, 2018 - Wiley Online Library
The ability of mechanochemistry to alter established chemical selectivity is demonstrated. A
copper (I)‐catalyzed mechanochemical aldehyde/alkyne/amine coupling using calcium …