Exploring hydroperoxides in combustion: History, recent advances and perspectives

Z Wang, O Herbinet, N Hansen… - Progress in Energy and …, 2019 - Elsevier
The aim of this paper is to review recent progress in detection and quantification of
hydroperoxides, and to understand their reaction kinetics in combustion environments …

Combustion in the future: The importance of chemistry

K Kohse-Höinghaus - Proceedings of the Combustion Institute, 2021 - Elsevier
Combustion involves chemical reactions that are often highly exothermic. Combustion
systems utilize the energy of chemical compounds released during this reactive process for …

Photoelectron photoion coincidence spectroscopy provides mechanistic insights in fuel synthesis and conversion

P Hemberger, A Bodi, T Bierkandt, M Köhler… - Energy & …, 2021 - ACS Publications
Clean combustion, ie, the reduction of NOx and soot emissions, and carbon neutrality,
achieved in part by biofuel synthesis, are major milestones in the transition to a sustainable …

Electron asymmetries in the photoionization of chiral molecules: possible astrophysical implications

R Hadidi, DK Bozanic, GA Garcia… - Advances in Physics …, 2018 - Taylor & Francis
Photoelectron circular dichroism (PECD) is an intense orbital-specific chiroptical effect
observed as asymmetries in the angular distribution of photoelectrons produced by …

Photodissociation and photoionization of molecules of astronomical interest-Updates to the Leiden photodissociation and photoionization cross section database

HR Hrodmarsson, EF Van Dishoeck - Astronomy & Astrophysics, 2023 - aanda.org
Context. Vacuum-ultraviolet (VUV) photons are important drivers of chemical processes in
space. Thus, it is important to accurately characterize and constrain photorates in different …

Gas-phase aluminium acetylacetonate decomposition: revision of the current mechanism by VUV synchrotron radiation

S Grimm, SJ Baik, P Hemberger, A Bodi… - Physical Chemistry …, 2021 - pubs.rsc.org
Although aluminium acetylacetonate, Al (C5H7O2) 3, is a common precursor for chemical
vapor deposition (CVD) of aluminium oxide, its gas-phase decomposition is not well-known …

The isomer distribution of C6H6 products from the propargyl radical gas-phase recombination investigated by threshold-photoelectron spectroscopy

HR Hrodmarsson, GA Garcia, L Bourehil… - Communications …, 2024 - nature.com
The resonance-stabilization of the propargyl radical (C3H3) makes it among the most
important reactive intermediates in extreme environments and grants it a long enough …

High-resolution double velocity map imaging photoelectron photoion coincidence spectrometer for gas-phase reaction kinetics

D Rosch, R Almeida, B Sztáray… - The Journal of Physical …, 2022 - ACS Publications
We present a new photoelectron photoion coincidence (PEPICO) spectrometer that
combines high mass resolution of cations with independently adjustable velocity map …

Isomer-sensitive characterization of low temperature oxidation reaction products by coupling a jet-stirred reactor to an electron/ion coincidence spectrometer: case of n …

J Bourgalais, Z Gouid, O Herbinet, GA Garcia… - Physical Chemistry …, 2020 - pubs.rsc.org
Through the use of tunable vacuum ultraviolet light generated by the DESIRS VUV
synchrotron beamline, a jet-stirred reactor was coupled for the first time to an advanced …

Product identification in the low-temperature oxidation of cyclohexane using a jet-stirred reactor in combination with SVUV-PEPICO analysis and theoretical quantum …

J Bourgalais, HH Carstensen, O Herbinet… - The Journal of …, 2022 - ACS Publications
Cyclohexane oxidation chemistry was investigated using a near-atmospheric pressure jet-
stirred reactor at T= 570 K and equivalence ratio ϕ= 0.8. Numerous intermediates including …