[HTML][HTML] From molecules to carbon materials—high pressure induced polymerization and bonding mechanisms of unsaturated compounds
X Yang, X Wang, Y Wang, K Li, H Zheng - Crystals, 2019 - mdpi.com
With the development of high-pressure apparatus, in situ characterization methods and
theoretical calculations, high-pressure technology becomes a more and more important …
theoretical calculations, high-pressure technology becomes a more and more important …
Solid-state pathway control via reaction-directing heteroatoms: ordered pyridazine nanothreads through selective cycloaddition
Nanothreads are one-dimensional nanomaterials composed of a primarily sp3 hydrocarbon
backbone, typically formed through the compression of small molecules to high pressures …
backbone, typically formed through the compression of small molecules to high pressures …
Evidence for Functionalized Carbon Nanothreads from π-Stacked, para-Disubstituted Benzenes
WS Tang, TA Strobel - The Journal of Physical Chemistry C, 2020 - ACS Publications
Recent studies of highly compressed organic molecules reveal the synthesis of one-
dimensional (1D) nanothread structures, typically formed through addition reactions of …
dimensional (1D) nanothread structures, typically formed through addition reactions of …
Modifying carbon nitride through extreme phosphorus substitution
A glassy carbon phosphonitride material with bulk chemical composition roughly
approximating C3N3P was synthesized through a high-pressure, high-temperature process …
approximating C3N3P was synthesized through a high-pressure, high-temperature process …
Tetracyanomethane under Pressure: Extended CN Polymers from Precursors with Built-in sp3 Centers
DW Keefer, H Gou, Q Wang, A Purdy… - The Journal of …, 2018 - ACS Publications
Tetracyanomethane, C (CN) 4, is a tetrahedral molecule containing a central sp3 carbon that
is coordinated by reactive nitrile groups that could potentially transform to an extended CN …
is coordinated by reactive nitrile groups that could potentially transform to an extended CN …
Surprising stability of cubane under extreme pressure
The chemical stability of solid cubane under high-pressure was examined with in situ
Raman spectroscopy and synchrotron powder X-ray diffraction (PXRD) in a diamond anvil …
Raman spectroscopy and synchrotron powder X-ray diffraction (PXRD) in a diamond anvil …
Pressure-induced solid-state polymerization of optically-tunable diphenyl-substituted diacetylene
WS Tang, TA Strobel - ACS Applied Polymer Materials, 2019 - ACS Publications
Solid-state topochemical polymerization (SSTP) requires well-defined geometries and
space symmetries between the starting monomers and resulting polymer, and diacetylenes …
space symmetries between the starting monomers and resulting polymer, and diacetylenes …
Double-Core Nanothread Formation from α-Furil via Pressure-Induced Planarization Pathway
The packing and geometry of compressed small molecule precursors largely dictate the
kinetically controlled formation processes of carbon nanothread materials. Structural …
kinetically controlled formation processes of carbon nanothread materials. Structural …
Stability of mixed carbon–silicon clathrates
We examine the thermodynamic and dynamic stability (ie, phonon dispersion) of mixed
silicon–carbon clathrate frameworks using first-principles calculations as a function of …
silicon–carbon clathrate frameworks using first-principles calculations as a function of …