The enantioconvergent cross-coupling of racemic alkyl halides represents a powerful tool for
the synthesis of enantioenriched molecules. In this regard, the first-row transition metal …

The C–O bond is ubiquitous in biologically active molecules, pharmaceutical agents, and
functional materials, thereby making it an important functional group. Consequently, the …

Atom transfer radical polymerization (ATRP) is a staple technique for the preparation of
polymers with well‐defined architecture. In ATRP, the catalyst governs the equilibrium …

Antibiotic pollution has become one of the most challenging environmental issues in aquatic
ecosystems, with adverse effects on human health. It is imperative to develop efficient …

In atom transfer radical polymerization (ATRP), radicals (R•) can react with CuI/L catalysts
forming organometallic complexes, R–CuII/L (L= N-based ligand). R–CuII/L favors additional …

Résumé This article surveys the current knowledge in metal alkyl complexes with
homolytically weak metal–carbon bonds, therefore prone to thermally produce alkyl radicals …

Organocopper (II) reagents are an unexplored frontier of copper catalysis. Despite being
proposed as reactive intermediates, an understanding of the stability and reactivity of the …

Cyanoisopropyl radicals, generated thermally by the decomposition of azobis
(isobutyronitrile)(AIBN), participate in reductive radical termination (RRT) under the …

Atom Transfer Radical Polymerization (ATRP), a metal‐catalyzed process, is a most
powerful method for macromolecular engineering, producing polymers with targeted and …

The termination processes of the tertiary carbomethoxyisopropyl radical,(COOMe) Me2C•,
have been investigated by 1H NMR under a variety of conditions. The radical was generated …