In the pursuit of new pharmaceuticals and agrochemicals, chemists in the life science
industry require access to mild and robust synthetic methodologies to systematically modify …

Organic compounds that show Thermally Activated Delayed Fluorescence (TADF) have
become wildly popular as next-generation emitters in organic light emitting diodes (OLEDs) …

This Perspective surveys the progress and current limitations of nucleophilic fluorination
methodologies. Despite the long and rich history of C (sp3)–F bond construction in chemical …

The past decade has witnessed the emergence of N-(acyloxy) phthalimides (NHPI esters)
and its derivatives at the forefront of synthetic methods facilitating the construction of diverse …

Bimolecular homolytic substitution (SH2) is an open-shell mechanism that is implicated
across a host of biochemical alkylation pathways. Surprisingly, however, this radical …

Decarboxylative halogenation, or halodecarboxylation, represents one of the fundamental
key methods for the synthesis of ubiquitous organic halides. The method is based on …

We demonstrate Markovnikov hydroalkoxylation of unactivated alkenes using alcohols
through a triple catalysis consisting of photoredox, cobalt, and Brønsted acid catalysts under …

The hydrofluorination of alkenes represents an attractive strategy for the synthesis of
aliphatic fluorides. This approach provides a direct means to form C (sp3)–F bonds …

Chemists are generally familiar with polar reactions and radical reactions, in comparison,
are underdeveloped. In the last few years, however, the novel concept of amalgamation of …

The direct and selective coupling of benzenes with aliphatic hydrocarbons is a promising
strategy for C (sp2)-C (sp3) bond formation using readily available starting materials, yet it …