Isolated transition metal clusters have been established as useful models for extended metal
surfaces or deposited metal particles, to improve the understanding of their surface …

Four seemingly simple transformations related to the chemistry of methane will be
addressed from mechanistic and conceptual points of view: 1) metal‐mediated …

Abstract Hydrogen‐atom transfer (HAT), as one of the fundamental reactions in chemistry, is
investigated with state‐of‐the‐art gas‐phase experiments in conjunction with computational …

This tutorial review presents the technique of infrared multiple-photon dissociation (IRMPD)
spectroscopy of mass-selected trapped ions. This requires coupling of a tunable infrared …

The low density of ions in mass spectrometers generally precludes direct infrared (IR)
absorption measurements. The IR spectrum of an ion can nonetheless be obtained by …

Dioxygen binding and activation at metal centers are of major importance in a wide range of
catalytic and biological processes. Metal oxides and dioxygen complexes are potential …

Mechanistic studies form the basis for a better understanding of chemical processes, helping
researchers develop more sustainable reactions by increasing the yields of the desired …

Cryogenic ion trap vibrational spectroscopy paired with quantum chemistry currently
represents the most generally applicable approach for the structural investigation of …

We are reporting a 3D printable composite paste having strong thixotropic rheology. The
composite has been designed and investigated with highly conductive silver nanowires. The …

Gas-phase infrared multiple photon dissociation (IRMPD) spectra have been recorded for
the conjugate bases of a series of amino acids (Asp, Cys, Glu, Phe, Ser, Trp, Tyr). The …