C–H functionalization has been emerging as a powerful method to establish carbon–carbon
and carbon–heteroatom bonds. Many efforts have been devoted to transition-metal …

The present review is devoted to summarizing the recent advances (2015–2017) in the field
of metal-catalysed group-directed C–H functionalisation. In order to clearly showcase the …

Transition-metal-catalyzed cross-coupling reactions have been well-established as
indispensable tools in modern organic synthesis. One of the major research goals in cross …

C–H bond activation and decarboxylation are two significant processes in organic synthesis.
The combination of these processes provides a novel synthetic strategy, that is …

C− H functionalization represents a paradigm shift from the standard logic of organic
synthesis. Instead of focusing on orchestration of selective reactions at functional groups, the …

The functionalization of carbon–hydrogen bonds in non‐nucleophilic substrates using α‐
carbonyl sulfoxonium ylides has not been so far investigated, despite the potential safety …

The first highly efficient and scalable cobalt‐catalyzed directed C H functionalization with
carbene precursors is presented. This methodology provides a modular route towards a new …

Sulfoxonium ylides act as an efficient carbene precursor in rhodium (III)-catalyzed C–H
acylmethlyation of a variety of arenes assisted by different chelating groups, and both aryl …

Cross-coupling reactions involving metal carbene migratory insertion have been established
as a new type of coupling reaction with diazo compounds as the reaction partners. Since …

Herein we describe the synthesis of a family of aryl-Co (III)-carboxylate complexes and their
reactivity with ethyl diazoacetate. Crystallographic, full spectroscopic characterization, and …