New approaches toward the hydrogen production from formic acid dehydrogenation over Pd-based heterogeneous catalysts
The urgency for finding clean energy sources is nowadays latent, and the role of hydrogen
in the future of energy is well-recognized. However, there are still various barriers that limit …
in the future of energy is well-recognized. However, there are still various barriers that limit …
An update on formic acid dehydrogenation by homogeneous catalysis
Formic acid (FA) has been extensively studied as one of the most promising hydrogen
energy carriers today. The catalytic decarboxylation of FA ideally leads to the formation of …
energy carriers today. The catalytic decarboxylation of FA ideally leads to the formation of …
Formic acid as a potential on‐board hydrogen storage method: Development of homogeneous noble metal catalysts for dehydrogenation reactions
J Guo, CK Yin, DL Zhong, YL Wang, T Qi… - …, 2021 - Wiley Online Library
Hydrogen can be used as an energy carrier for renewable energy to overcome the
deficiency of its intrinsically intermittent supply. One of the most promising application of …
deficiency of its intrinsically intermittent supply. One of the most promising application of …
CO2 Hydrogenation and Formic Acid Dehydrogenation Using Ir Catalysts with Amide-Based Ligands
A series of Ir catalysts bearing amide-based ligands generated by a deprotonated amide
moiety was prepared with the hypotheses that the strong electron-donating ability of the …
moiety was prepared with the hypotheses that the strong electron-donating ability of the …
Electronic and Steric Tuning of Catalytic H2 Evolution by Cobalt Complexes with Pentadentate Polypyridyl-Amine Ligands
Structural modifications of molecular cobalt catalysts have provided important insights into
the structure–function relationship for the hydrogen evolution reaction. We have shown that …
the structure–function relationship for the hydrogen evolution reaction. We have shown that …
Performance of homogeneous catalysts viewed in dynamics
Effective assessment of catalytic performance is the foundation for the rational design and
development of new catalysts with superior performance. The ubiquitous …
development of new catalysts with superior performance. The ubiquitous …
Design of Ru (II)-NHC-diamine precatalysts directed by ligand cooperation: applications and mechanistic investigations for asymmetric hydrogenation
W Li, T Wagener, L Hellmann, CG Daniliuc… - Journal of the …, 2020 - ACS Publications
A modular synthesis of Ru (II)-NHC-diamine complexes from readily available chiral N-
heterocyclic carbenes (NHCs) and chiral diamines is disclosed for the first time. The well …
heterocyclic carbenes (NHCs) and chiral diamines is disclosed for the first time. The well …
Selective Photocatalytic Dehydrogenation of Formic Acid by an In Situ-Restructured Copper-Postmetalated Metal–Organic Framework under Visible Light
Formic acid is considered as one of the most promising liquid organic hydrogen carriers. Its
catalytic dehydrogenation process generally suffers from low activity, low reaction selectivity …
catalytic dehydrogenation process generally suffers from low activity, low reaction selectivity …
Cyclic Amide-Anchored NHC-Based Cp*Ir Catalysts for Bidirectional Hydrogenation–Dehydrogenation with CO2/HCO2H Couple
H2 storage in carbon dioxide (CO2) or bicarbonate (HCO3–) in the form of formic acid
(HCO2H) or formate (HCO2–) and the reverse H2 liberation allows, in principle, to develop a …
(HCO2H) or formate (HCO2–) and the reverse H2 liberation allows, in principle, to develop a …
Advances in nonprecious metal homogeneously catalyzed formic acid dehydrogenation
M Iglesias, FJ Fernández-Alvarez - Catalysts, 2021 - mdpi.com
Formic acid (FA) possesses a high volumetric concentration of H2 (53 g L− 1). Moreover, it
can be easily prepared, stored, and transported. Therefore, FA stands out as a potential …
can be easily prepared, stored, and transported. Therefore, FA stands out as a potential …