As interest has grown in electron-transfer (ET) reactions of organometallic compounds, so
too has the use of chemical oxidizing and reducing agents to effect these transformations …

One of the most exciting developments in the areas of catalysis, organometallic chemistry,
and polymer science in recent years has been the intense exploration and …

Current studies on novel, metallocenebased catalysts for the polymerization of α‐olefins
have far‐reaching implications for the development of new materials as well as for the …

Cationic alkyl complexes of Group 4 metallocenes of the type [MCp2R]+(M= Ti, Zr or Hf, Cp=
C5H5) have been recognised as the catalytically active species in metallocene-based olefin …

Publisher Summary This chapter discusses the chemistry of cationic dicyclopentadienyl
group 4 metal–alkyl complexes. Neutral, d 0 group 4 metal alkyl complexes of general form …

The extension of the frustrated Lewis pair (FLP) concept to the transition series with cationic
zirconocene–phosphinoaryloxide complexes is demonstrated. Such complexes mimic the …

Untersuchungen an neuen Metallocenkatalysatoren zur Polymerisation von α‐Olefinen
haben gegenwärtig weitreichende Auswirkungen auf die Entwicklung neuer Materialien und …

A new range of metallocene catalysts, Cp 2 MCl 2 (M= Ti, Zr, Hf) has been developed in the
past decade, which, in the presence of alumoxanes are highly efficient at polymerizing α …

The discovery of transition metal-catalysed polymerisation of olefins in the 1950s by Ziegler
and Natta was of huge importance. Over the last 30 years, the interest in homogenous …

The preparation and reaction chemistry of β-diketiminato aluminum complexes are
described.(TTP) AlCl2 (1)(TTPH= 2-(p-tolylamino)-4-(p-tolylimino)-2-pentene) is formed by …