Long persistent luminescence from metal–organic compounds: state of the art

B Zhou, D Yan - Advanced Functional Materials, 2023 - Wiley Online Library
The excited‐state tuning of luminescent metal–organic compounds has made great
progress in the fields of optical imaging, photocatalysis, photodynamic therapy, light …

Photoactive Metal-to-Ligand Charge Transfer Excited States in 3d6 Complexes with Cr0, MnI, FeII, and CoIII

N Sinha, OS Wenger - Journal of the American Chemical Society, 2023 - ACS Publications
Many coordination complexes and organometallic compounds with the 4d6 and 5d6
valence electron configurations have outstanding photophysical and photochemical …

Luminescent and photofunctional transition metal complexes: From molecular design to diagnostic and therapeutic applications

LCC Lee, KKW Lo - Journal of the American Chemical Society, 2022 - ACS Publications
There has been emerging interest in the exploitation of the photophysical and
photochemical properties of transition metal complexes for diagnostic and therapeutic …

Phototherapeutic anticancer strategies with first-row transition metal complexes: a critical review

L Gourdon, K Cariou, G Gasser - Chemical Society Reviews, 2022 - pubs.rsc.org
Photodynamic therapy (PDT) and photoactivated chemotherapy (PACT) are therapeutic
techniques based on a photosensitizer (PS) and light. These techniques allow the spatial …

Photoredox-active Cr (0) luminophores featuring photophysical properties competitive with Ru (II) and Os (II) complexes

N Sinha, C Wegeberg, D Häussinger, A Prescimone… - Nature Chemistry, 2023 - nature.com
Coordination complexes of precious metals with the d6 valence electron configuration such
as Ru (II), Os (II) and Ir (III) are used for lighting applications, solar energy conversion and …

Multiplicative enhancement of stereoenrichment by a single catalyst for deracemization of alcohols

L Wen, J Ding, L Duan, S Wang, Q An, H Wang, Z Zuo - Science, 2023 - science.org
Stereochemical enrichment of a racemic mixture by deracemization must overcome
unfavorable entropic effects as well as the principle of microscopic reversibility; recently …

The great strides of iron photosensitizers for contemporary organic photoredox catalysis: On our way to the holy grail?

F Glaser, A Aydogan, B Elias… - Coordination Chemistry …, 2024 - Elsevier
The scarcity of 2 nd and 3 rd row transition metals such as ruthenium, iridium, rhodium and
osmium, coupled with a global desire for sustainable chemistry has led to the resurgence of …

Capturing dynamic ligand-to-metal charge transfer with a long-lived cationic intermediate for anionic redox

B Li, K Kumar, I Roy, AV Morozov, OV Emelyanova… - Nature Materials, 2022 - nature.com
Reversible anionic redox reactions represent a transformational change for creating
advanced high-energy-density positive-electrode materials for lithium-ion batteries. The …

Red light-based dual photoredox strategy resembling the Z-scheme of natural photosynthesis

F Glaser, OS Wenger - JACS Au, 2022 - ACS Publications
Photoredox catalysis typically relies on the use of single chromophores, whereas strategies,
in which two different light absorbers are combined, are rare. In photosystems I and II of …

Stable Molybdenum (0) carbonyl complex for upconversion and photoredox catalysis

WR Kitzmann, MS Bertrams, P Boden… - Journal of the …, 2023 - ACS Publications
Photoactive complexes with earth-abundant metals have attracted increasing interest in the
recent years fueled by the promise of sustainable photochemistry. However, sophisticated …