N-Heterocyclic carbene complexes in C–H activation reactions

Q Zhao, G Meng, SP Nolan, M Szostak - Chemical reviews, 2020 - ACS Publications
In this contribution, we provide a comprehensive overview of C–H activation methods
promoted by NHC–transition metal complexes, covering the literature since 2002 (the year …

3d transition metals for C–H activation

P Gandeepan, T Müller, D Zell, G Cera… - Chemical …, 2018 - ACS Publications
C–H activation has surfaced as an increasingly powerful tool for molecular sciences, with
notable applications to material sciences, crop protection, drug discovery, and …

N-Heterocyclic carbenes as privileged ligands for nickel-catalysed alkene functionalisation

BC Lee, CF Liu, LQH Lin, KZ Yap, NX Song… - Chemical Society …, 2023 - pubs.rsc.org
Alkene functionalisation is a powerful strategy that has enabled access to a wide array of
compounds including valuable pharmaceuticals and agrochemicals. The reactivity of the …

Transition-metal-catalyzed C–H bond alkylation using olefins: recent advances and mechanistic aspects

D Mandal, S Roychowdhury, JP Biswas… - Chemical Society …, 2022 - pubs.rsc.org
Transition metal catalysis has contributed immensely to C–C bond formation reactions over
the last few decades, and alkylation is no exception. The superiority of such methodologies …

N-heterocyclic carbene complexes of copper, nickel, and cobalt

AA Danopoulos, T Simler, P Braunstein - Chemical reviews, 2019 - ACS Publications
The emergence of N-heterocyclic carbenes as ligands across the Periodic Table had an
impact on various aspects of the coordination, organometallic, and catalytic chemistry of the …

Stable abnormal N-heterocyclic carbenes and their applications

SC Sau, PK Hota, SK Mandal, M Soleilhavoup… - Chemical Society …, 2020 - pubs.rsc.org
Although N-heterocyclic carbenes (NHCs) have been known as ligands for organometallic
complexes since the 1960s, these carbenes did not attract considerable attention until …

Nickel-catalyzed C− H functionalization using a non-directed strategy

SM Khake, N Chatani - Chem, 2020 - cell.com
The activation of ubiquitous C–H bonds has great significance in the field of organic
synthesis given that it represents an ideal method for directly producing valuable chemicals …

Recent advances and prospects in nickel-catalyzed C–H activation

NA Harry, S Saranya, SM Ujwaldev… - Catalysis Science & …, 2019 - pubs.rsc.org
Nickel-catalyzed C–H activation has become a predominant and ubiquitous research area
in organic chemistry. Direct functionalization of inert C–H bonds to create functionally …

Recent developments in transition-metal catalyzed direct C–H alkenylation, alkylation, and alkynylation of azoles

S Chen, P Ranjan, LG Voskressensky… - Molecules, 2020 - mdpi.com
The transition metal-catalyzed C–H bond functionalization of azoles has emerged as one of
the most important strategies to decorate these biologically important scaffolds. Despite …

Ni/NHC catalysis in C–H functionalization using air-tolerant nickelocene and sodium formate for in situ catalyst generation

OV Khazipov, KE Shepelenko, DV Pasyukov… - Organic Chemistry …, 2021 - pubs.rsc.org
C–H functionalization in the area of fine organic synthesis is dominated by noble metal
catalysts, which represent the most expensive and least sustainable options. Sustainable C …